New selective haloform-type reaction yielding 3-hydroxy-2,2-difluoroacids : Theoretical study of the mechanism
- Author
- OLIVELLA, Santiago; SOLE, Albert; JIMENEZ, Oscar; BOSCH, M. Pilar; GUERRERO, Angel
Centre Especial de Recerca en Quimica Teòrica i Departament de Química Física, Universitat de Barcelona, Martí i Franquès 1, 08028-Barcelona, Catalonia, Spain
Departament de Quimica Orgànica Biològica, Institut d'Investigacions Químiques i Ambientals de Barcelona, CSIC, Jordi Girona 18, 08034-Barcelona, Catalonia, Spain - Source
Journal of the American Chemical Society. 2005, Vol 127, Num 8, pp 2620-2627, 8 p ; ref : 23 ref
- CODEN
- JACSAT
- ISSN
- 0002-7863
- Scientific domain
- Biochemistry, molecular biology, biophysics; Chemistry; Organic chemistry; Atomic molecular physics
- Publisher
- American Chemical Society, Washington, DC
- Publication country
- United States
- Document type
- Article
- Language
- English
- Keyword (fr)
- Barrière énergie Etat transition Etude théorique Hydroxyde Méthode fonctionnelle densité Paramètre thermodynamique Réaction ion molécule Réaction phase gazeuse Schéma réactionnel Butyrique acide(2,2-difluoro-3-hydroxy) Fluoroforme Pentan-2-one(4-hydroxy-1,1,1,3,3-pentafluoro)
- Keyword (en)
- Energy barrier Transition state Theoretical study Hydroxides Density functional method Thermodynamic parameter Ion molecule reaction Gaseous phase reaction Reaction path
- Keyword (es)
- Barrera energía Estado transitorio Estudio teórico Hidróxido Parámetro termodinámico Reacción ión molécula Reacción fase gaseosa Esquema reacciones
- Classification
- Pascal
- 001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03B Reactivity and mechanisms / 001C03B02 Kinetics and mechanisms
- Discipline
- Organic chemistry
- Origin
- Inist-CNRS
- Database
- PASCAL
- INIST identifier
- 16578829
Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS
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DOI
10.1021/ja043522d 
https://dx.doi.org/10.1021/ja043522d
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