Intermediates of halogen addition to phenylethynes and protonation of phenylethynyl halides. open halovinyl cations, bridged halonium, or phenyl-bridged ions : A substituent effect study by DFT and GIAO-DFT
- Author
- OKAZAKI, Takao1 2 ; LAALI, Kenneth K1
[1] Department of Chemistry, Kent State University, Kent, Ohio 44242, United States
[2] Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto 615-8510, Japan - Source
Journal of organic chemistry. 2006, Vol 71, Num 26, pp 9643-9650, 8 p ; ref : 12 ref
- CODEN
- JOCEAH
- ISSN
- 0022-3263
- Scientific domain
- Biochemistry, molecular biology, biophysics; Organic chemistry
- Publisher
- American Chemical Society, Washington, DC
- Publication country
- United States
- Document type
- Article
- Language
- English
- Keyword (fr)
- Cation Cinétique Composé acétylénique Composé aromatique Composé cyclique Composé vinylique Dication organique Déplacement chimique Effet substituant Etude comparative Halogène composé organique Halogène composé Méthode fonctionnelle densité Protonation Solvolyse Spectrométrie RMN Spirane Stabilité Structure électronique Synthèse chimique
- Keyword (en)
- Cations Kinetics Acetylenic compound Aromatic compound Cyclic compound Vinylic compound Organic dication Chemical shift Substituent effect Comparative study Organic halogen compounds Halogen compound Density functional method Protonation Solvolysis NMR spectrometry Spiran Stability Electronic structure Chemical synthesis
- Keyword (es)
- Cation Cinética Compuesto acetilénico Compuesto aromático Compuesto cíclico Compuesto vinílico Dicatión orgánico Desplazamiento químico Efecto sustituyente Estudio comparativo Halogeno compuesto Protonación Solvolisis Espectrometría RMN Espirano Estabilidad Estructura electrónica Síntesis química
- Classification
- Pascal
- 001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03B Reactivity and mechanisms / 001C03B02 Kinetics and mechanisms
- Discipline
- Organic chemistry
- Origin
- Inist-CNRS
- Database
- PASCAL
- INIST identifier
- 18367089
Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS
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DOI
10.1021/jo061632s 
https://dx.doi.org/10.1021/jo061632s
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