2-Pyridylnitrene and 3-Pyridazylcarbene and Their Relationship via Ring-Expansion, Ring-Opening, Ring-Contraction, and Fragmentation
- Author
- KVASKOFF, David1 ; BEDNAREK, Pawel1 ; WENTRUP, Curt1
[1] School of Chemistry and Molecular Biosciences, The University of Queensland, Brisbane, Qld 4072, Australia - Source
Journal of organic chemistry. 2010, Vol 75, Num 5, pp 1600-1611, 12 p
- CODEN
- JOCEAH
- ISSN
- 0022-3263
- Scientific domain
- Biochemistry, molecular biology, biophysics; Organic chemistry
- Publisher
- American Chemical Society, Washington, DC
- Publication country
- United States
- Document type
- Article
- Language
- English
- Keyword (fr)
- Agrandissement cycle Analyse structurale Azide Carbène Composé acétylénique Composé diazoïque Composé diynique Composé énynique Contraction cycle Cumulène Diradical libre organique Décyclisation Dérivé de la pyridazine Dérivé de la pyridine Etat singulet Etat triplet Etude théorique Fragmentation Hétérocycle azote Isolement matrice Mécanisme réaction Méthode CAS SCF Méthode fonctionnelle densité Méthode perturbation Nitrile Nitrène Photolyse Pyrolyse éclair Réaction concertée Spectrométrie IR Spectrométrie RPE Spectrométrie UV Transposition chimique 1,3-Diazacyclohepta-1,2,4,6-tétraène dérivé 1,4-Diazaspiro[2.4]hepta-1,4,6-triène dérivé Cyclopropène dérivé Tétrazolo[1,5-a]pyridine dérivé
- Keyword (en)
- Ring expansion Structural analysis Organic azide Carbene Acetylenic compound Diazo compound Diynic compound Enynic compound Ring contraction Cumulene Organic free biradical Ring cleavage Pyridazine derivatives Pyridine derivatives Singlet state Triplet state Theoretical study Fragmentation Nitrogen heterocycle Matrix isolation Reaction mechanism CAS SCF method Density functional method Perturbation method Nitrile Nitrene Photolysis Flash pyrolysis Concerted reaction Infrared spectrometry EPR spectrometry Ultraviolet spectrometry Chemical rearrangement
- Keyword (es)
- Expansión anillo Análisis estructural Azida orgánica Carbeno Compuesto acetilénico Compuesto diazoico Compuesto diínico Compuesto enínico Contracción ciclo Cumuleno Dirradical libre orgánico Desciclización Piridazina derivado Piridina derivado Estado singular Estado triplete Estudio teórico Fragmentación Heterociclo nitrógeno Aislamiento matriz Mecanismo reacción Método CAS SCF Método perturbación Nitrilo Nitreno Fotolisis Pirolisis rápida Reacción concertada Espectrometría IR Espectrometría RPE Espectrometría UV Transposición química
- Classification
- Pascal
- 001 Exact sciences and technology / 001C Chemistry / 001C01 General and physical chemistry / 001C01F Physical chemistry of induced reactions (with radiations, particles and ultrasonics) / 001C01F01 Photochemistry
- Pascal
- 001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03B Reactivity and mechanisms / 001C03B02 Kinetics and mechanisms
- Pascal
- 001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03B Reactivity and mechanisms / 001C03B04 Free radicals chemistry
- Pascal
- 001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03C Preparations and properties / 001C03C06 Heterocyclic compounds / 001C03C06C Heterocyclic compounds with several n hetero atoms in the same ring, in separated rings or in fused rings
- Discipline
- General chemistry and physical chemistry Organic chemistry
- Origin
- Inist-CNRS
- Database
- PASCAL
- INIST identifier
- 22545462
Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS
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DOI
10.1021/jo902570d 
https://dx.doi.org/10.1021/jo902570d
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