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A biomimetic synthesis of (―)-ascorbyl phloroglucinol and studies toward the construction of ascorbyl-modified catechin natural products and analogues

Author
BELAPURE, Sneha A1 ; BEAMER, Zachary G1 ; BARTMESS, John E1 ; CAMPAGNA, Shawn R1
[1] Department of Chemistry, University of Tennessee, Knoxville, TN 37996-1600, United States
Source

Tetrahedron (Oxford. Print). 2011, Vol 67, Num 48 ; 9225, 9265-9272 [9 p.]

CODEN
TETRAB
ISSN
0040-4020
Scientific domain
Organic chemistry
Publisher
Elsevier, Kidlington
Publication country
United Kingdom
Document type
Article
Language
English
Author keyword
(―)-Ascorbyl phloroglucinol Ascorbyl epigallocatechin Ascorbylation reaction Chemoselective reaction Stereoselective reaction
Keyword (fr)
Acide acétique Acide ascorbique Acide phénolique Catalyse acide Catéchine Chimiosélectivité Composé biomimétique Composé naturel Composé tétracyclique Donneur électron Dérivé de l'acide gallique Epimère Flavonoïde Hétérocycle oxygène Liaison carbone carbone Liaison chimique Phénols Polyphénol Régiosélectivité Stéréosélectivité Synthèse chimique Acide déhydroascorbique Epigallocatéchine Phloroglucinol dérivé
Keyword (en)
Acetic acid Ascorbic acid Phenolic acid Acid catalysis Catechin Chemoselectivity Biomimetic compound Natural compound Tetracyclic compound Electron donor Gallic acid derivatives Epimer Flavonoid Oxygen heterocycle Carbon carbon bond Chemical bond Phenols Polyphenol Regioselectivity Stereoselectivity Chemical synthesis
Keyword (es)
Acético ácido Acido ascórbico Acido fenólico Catálisis ácida Catequina Quimioselectividad Compuesto biomimético Compuesto natural Compuesto tetracíclico Donador electrón Gálico ácido derivado Epímero Flavonoide Heterociclo oxígeno Enlace carbono carbono Enlace químico Fenoles Polifenol Regioselectividad Estereoselectividad Síntesis química
Classification
Pascal
001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03C Preparations and properties / 001C03C03 Noncondensed benzenic compounds

Pascal
001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03C Preparations and properties / 001C03C06 Heterocyclic compounds / 001C03C06A Heterocyclic compounds with o, s, se, te hetero atom and condensed derivatives

Discipline
Organic chemistry
Origin
Inist-CNRS
Database
PASCAL
INIST identifier
25489314

Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS

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