Diastereoselective ene reaction in the photooxygenation of the silyl cyanohydrins of α,β-unsaturated aldehydes: necessity for a common symmetrical intermediate of the perepoxide type
- Author
- ADAM, W1 ; CATALANI, L. H; GRIESBECK, A
[1] Univ. Würzburg, inst. organische chemie, Würzburg 8700, Germany - Source
Journal of organic chemistry. 1986, Vol 51, Num 26, pp 5494-5496 ; ref : 10 ref
- CODEN
- JOCEAH
- ISSN
- 0022-3263
- Scientific domain
- Biochemistry, molecular biology, biophysics; Organic chemistry
- Publisher
- American Chemical Society, Washington, DC
- Publication country
- United States
- Document type
- Article
- Language
- English
- Keyword (fr)
- Composé aliphatique Composé éthylénique Diastéréosélectivité Etat singulet Ether Oxygène Oxygénation Réaction photochimique Réaction ène Silicium Composé organique Butène-«3»nitrile(«t»-butyldiméthylsiloxy-«2» hydroperoxy-«1» éthyl-«3») Pentène-3nitrile(méthyl-«4» triméthylsiloxy-«2») Pentène-«3»nitrile(«t»-butyldiméthylsiloxy-«2» méthyl-«3») Pentène-«4»nitrile(hydroxypéroxy-«3» méthyl-«4» triméthylsiloxy-«2»)
- Keyword (en)
- Aliphatic compound Ethylenic compound Diastereoselectivity Singlet state Ether Oxygen Oxygenation Photochemical reaction Ene reaction Silicon Organic compounds
- Keyword (es)
- Compuesto alifatico Compuesto etilénico Diastereoselectividad Estado singular Eter Oxígeno Oxigenacion Reacción fotoquímica Reacción ene Silicio
- Classification
- Pascal
- 001 Exact sciences and technology / 001C Chemistry / 001C01 General and physical chemistry / 001C01F Physical chemistry of induced reactions (with radiations, particles and ultrasonics) / 001C01F01 Photochemistry
- Discipline
- General chemistry and physical chemistry
- Origin
- Inist-CNRS
- Database
- PASCAL
- INIST identifier
- 8228286
Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS
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DOI
10.1021/jo00376a105 
https://dx.doi.org/10.1021/jo00376a105
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