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Direct evidence supporting a dimer structure of stable radical intermediate appeared in the Grignard reaction

Author
MARUYAMA, K1 ; KATAGIRI, T
[1] Kyoto univ., fac. sci., dep. chemistry, Sakyo-ku Kyoto 606, Japan
Source

Chemistry Letters. 1987, Num 4, pp 731-734 ; ref : 9 ref

CODEN
CMLTAG
ISSN
0366-7022
Scientific domain
Chemistry; Atomic molecular physics
Publisher
Chemical Society of Japan, Tokyo
Publication country
Japan
Document type
Article
Language
English
Keyword (fr)
Composé benzénique Cétone Dimère Intermédiaire réaction Magnésium Composé organique Radical libre organique anionique Réaction Grignard Spectrométrie RPE Transfert électron Benzophénone(méthyl-2) Furanne(méthyl-«2» perhydro) Magnésium(éthyl) bromure THF
Keyword (en)
Benzenic compound Ketone Dimer Reaction intermediate Magnesium Organic compounds Organic radical anion Grignard reaction EPR spectrometry Electron transfer
Keyword (es)
Compuesto bencénico Cetona Dimero Intermediario reaccion Magnesio Radical libre orgánico aniónico Reacción Grignard Espectrometria RPE Transferencia electron
Classification
Pascal
001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03B Reactivity and mechanisms / 001C03B02 Kinetics and mechanisms

Discipline
Organic chemistry
Origin
Inist-CNRS
Database
PASCAL
INIST identifier
8349790

Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS

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