A DIRECTING EFFECT OF NEIGHBORING AROMATIC GROUPS ON THE REGIOCHEMISTRY OF FORMATION AND ON THE STEREOCHEMISTRY OF ALKYLATION AND BROMINATION OF KETONE LITHIUM ENOLATES. EVIDENCE FOR LITHIUM-ARENE PI COORDINATION AND FOR A DRAMATIC EFFECT OF EVEN SMALL AMOUNTS OF COPPER(I) IN CONTROLLING STEREOCHEMISTRY AND IN LIMITING POLYALKYLATION
- Author
- POSNER GH; LENTZ CM
JOHNS HOPKINS UNIV. DEP. CHEM., BALTIMORE MD 21218, USA - Source
- J. AMER. CHEM. SOC.; USA; DA. 1979; VOL. 101; NO 4; PP. 934-946; BIBL. 66 REF.
- Document type
- Article
- Language
- English
- Keyword (fr)
- EFFET GROUPE VOISIN ENOLISATION METHYLATION SILICIUM COMPOSE ORGANIQUE BROMATION COMPOSE MONOCYCLIQUE COMPOSE ETHYLENIQUE ENONE ENOL ETHER CETONE CUIVRE I CYANURE!ACT COMPOSE ALIPHATIQUE CYCLOPENTANONE(METHYL-3 PHENYL-3)!ENT CYCLOPENTENE(METHYL-3 PHENYL-3 TRIMETHYLSILOXY-1)!ENT CYCLOPENTENE-2ONE(PHENYL-3)!ENT CYCLOPENTANONE(DIMETHYL-2,3 PHENYL-3)!FIN CYCLOPENTENE(PHENYL-3 TRIMETHYLSILOXY-1)!ENT CYCLOPENTANONE(ALLYL-2 PHENYL-3)!FIN CYCLOPENTANONE(BROMO-2 METHYL-3 PHENYL-3)!FIN HEXANONE-3(P-TOLYL-5)!ENT CYCLOHEXANONE(BENZYL-3 METHYL-3)!ENT CYCLOHEXANONE(BUTYL-3 METHYL-3)!ENT CYCLOPENTANEACETIQUE ACIDE(METHYL-1 OXO-2 PHENYL-5) ESTER METHYLE!FIN ACETIQUE ACIDE(BROMO) ESTER METHYLE!ENT CUIVRE-LITHIUM(DIPHENYL)!ENT SILANE(CHLORO TRIMETHYL)!ENT LITHIUM AMIDURE(DIISOPROPYL)!ENT THF!SUB CHIMIE ORGANIQUE
- Keyword (en)
- NEIGHBOURING GROUP EFFECT ENOLIZATION METHYLATION BROMINATION MONOCYCLIC COMPOUND ETHYLENIC COMPOUND ENONE ENOL ETHER KETONE ALIPHATIC COMPOUND ORGANIC CHEMISTRY
- Keyword (es)
- QUIMICA ORGANICA
- Classification
- Discipline
- General chemistry and physical chemistry
- Origin
- Inist-CNRS
- Database
- PASCAL
- INIST identifier
- PASCAL7960285036
Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS
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