Steric effects and solvent effects in ionic reactions
- Author
- REGAN, Colleen K1 ; CRAIG, Stephen L2 ; BRAUMAN, John I3
[1] Department of Chemistry, Bryn Mawr College, Bryn Mawr, PA 19010, United States
[2] Department of Chemistry, Duke University, Durham, NC 27708, United States
[3] Department of Chemistry, Stanford University, Stanford, CA 94305-5080, United States - Source
Science (Washington, D.C.). 2002, Vol 295, Num 5563, pp 2245-2247
- CODEN
- SCIEAS
- ISSN
- 0036-8075
- Scientific domain
- Multidisciplinary
- Publisher
- American Association for the Advancement of Science, Washington, DC
- Publication country
- United States
- Document type
- Article
- Language
- English
- Keyword (fr)
- Chlorure Cinétique Composé aliphatique Echange isotopique Effet solvant Effet stérique Etude théorique Mécanisme SN2 Méthode Monte Carlo Nitrile Phase gazeuse Phase liquide Réaction ion molécule Spectrométrie cyclotronique ionique Spectrométrie masse Théorie RRKM Transformation Fourier Butyronitrile(2-chloro-3,3-diméthyl) Propionitrile(2-chloro)
- Keyword (en)
- Chlorides Kinetics Aliphatic compound Isotope exchange Solvent effect Steric effect Theoretical study SN2 mechanism Monte Carlo method Nitrile Gas phase Liquid phase Ion molecule reaction Ion cyclotron resonance spectrometry Mass spectrometry RRKM theory Fourier transformation
- Keyword (es)
- Cloruro Cinética Compuesto alifático Intercambio isotópico Efecto solvente Efecto estérico Estudio teórico Mecanismo SN2 Método Monte Carlo Nitrilo Fase gaseosa Fase líquida Reacción ión molécula Espectrometría ciclotrónica iónica Espectrometría masa Teoría RRKM Transformación Fourier
- Classification
- Pascal
- 001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03B Reactivity and mechanisms / 001C03B03 Mass spectrometry
- Pascal
- 001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03C Preparations and properties / 001C03C02 Aliphatic compounds
- Discipline
- Organic chemistry
- Origin
- Inist-CNRS
- Database
- PASCAL
- INIST identifier
- 13579335
Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS
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DOI
10.1126/science.1068849 
https://dx.doi.org/10.1126/science.1068849
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