The first complete identification of a diastereomeric catalyst-substrate (alkoxide) species in an enantioselective ketone hydrogenation. Mechanistic investigations
- Author
- DALEY, Christopher J. A1 ; BERGENS, Steven H1
[1] Department of Chemistry, University of Alberta, Edmonton, Alberta T6G 2G2, Canada - Source
Journal of the American Chemical Society. 2002, Vol 124, Num 14, pp 3680-3691
- CODEN
- JACSAT
- ISSN
- 0002-7863
- Scientific domain
- Biochemistry, molecular biology, biophysics; Chemistry; Organic chemistry; Atomic molecular physics
- Publisher
- American Chemical Society, Washington, DC
- Publication country
- United States
- Document type
- Article
- Language
- English
- Keyword (fr)
- Activité catalytique Catalyseur complexe Coordinat organique Diester Enantiosélectivité Etude expérimentale Hydrogénation Mécanisme réaction Ruthénium Complexe Réaction catalytique Spectrométrie RMN Sélectivité catalyseur Succinique acide(3,3-diméthyl-2-oxo) ester dialkyle Métal transition Complexe Platinoïde Complexe
- Keyword (en)
- Catalyst activity Complex catalyst Organic ligand Diester Enantioselectivity Experimental study Hydrogenation Reaction mechanism Ruthenium Complexes Catalytic reaction NMR spectrometry Catalyst selectivity Transition metal Complexes Platinoid Complexes
- Keyword (es)
- Actividad catalítica Catalizador complejo Ligando orgánico Diester Enantioselectividad Estudio experimental Hidrogenación Mecanismo reacción Rutenio Complejo Reacción catalítica Espectrometría RMN Selectividad catalizador Metal transición Complejo Platinoide Complejo
- Classification
- Pascal
- 001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03B Reactivity and mechanisms / 001C03B02 Kinetics and mechanisms
- Discipline
- Organic chemistry
- Origin
- Inist-CNRS
- Database
- PASCAL
- INIST identifier
- 13603271
Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS
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DOI
10.1021/ja0102991 
https://dx.doi.org/10.1021/ja0102991
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