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Stereoselective formation of glycosyl sulfoxides and their subsequent equilibration: Ring inversion of an α-xylopyranosyl sulfoxide dependent on the configuration at sulfur

Author
CRICH, David1 ; MATAKA, Jan1 ; ZAKHAROV, Lev N2 ; RHEINGOLD, Arnold L2 ; WINK, Donald J1
[1] Department of Chemistry, University of Illinois at Chicago, 845 West Taylor Street, Chicago, Illinois 60607-7061, United States
[2] Department of Chemistry and Biochemistry, University of Delaware, Academy Street, Newark, Delaware 19716, United States
Source

Journal of the American Chemical Society. 2002, Vol 124, Num 21, pp 6028-6036

CODEN
JACSAT
ISSN
0002-7863
Scientific domain
Biochemistry, molecular biology, biophysics; Chemistry; Organic chemistry; Atomic molecular physics
Publisher
American Chemical Society, Washington, DC
Publication country
United States
Document type
Article
Language
English
Keyword (fr)
Etude expérimentale Interaction moléculaire Inversion conformation Isomérie rotation Paramètre thermodynamique Réactivité chimique Spectrométrie RMN Stéréosélectivité Sulfoxyde Thioglycoside 1-Thioxylopyranoside dérivé
Keyword (en)
Experimental study Molecular interaction Conformation inversion Rotational isomerism Thermodynamic parameter Chemical reactivity NMR spectrometry Stereoselectivity Sulfoxide Thioglycoside
Keyword (es)
Estudio experimental Interacción molecular Inversión conformación Isomería rotación Parámetro termodinámico Reactividad química Espectrometría RMN Estereoselectividad Sulfóxido Tioglicósido
Classification
Pascal
001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03B Reactivity and mechanisms / 001C03B01 Chemical reactivity

Discipline
Organic chemistry
Origin
Inist-CNRS
Database
PASCAL
INIST identifier
13685268

Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS

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