A warning on the use of radical traps as a test for radical mechanisms: They react with palladium hydrido complexes
- Author
- ALBENIZ, Ana C1 ; ESPINET, Pablo1 ; LOPEZ-FERNANDEZ, Raquel1 ; AYUSMAN SEN2
[1] Departamento de Química Inorgánica, Facultad de Ciencias, Universidad de Valladolid, 47005 Valladolid, Spain
[2] Department of Chemistry, The Pennsylvania State University, University Park, Pennsylvania 16802, United States - Source
Journal of the American Chemical Society. 2002, Vol 124, Num 38, pp 11278-11279, 2 p ; ref : 12 ref
- CODEN
- JACSAT
- ISSN
- 0002-7863
- Scientific domain
- Biochemistry, molecular biology, biophysics; Chemistry; Organic chemistry; Atomic molecular physics
- Publisher
- American Chemical Society, Washington, DC
- Publication country
- United States
- Document type
- Article
- Language
- English
- Keyword (fr)
- Complexe chloro Complexe hydruro Composé benzénique Contrôle cinétique Coordinat organique Etude expérimentale Mécanisme réaction Palladium Complexe Phosphine tertiaire Radical libre organique Réaction molécule radical Transfert hydrure Galvinoxyle Phosphine(triphényl) Métal transition Complexe Platinoïde Complexe
- Keyword (en)
- Chloro complex Hydrido complex Benzenic compound Kinetic control Organic ligand Experimental study Reaction mechanism Palladium Complexes Tertiary phosphine Organic free radical Molecule radical reaction Hydride transfer Transition metal Complexes Platinoid Complexes
- Keyword (es)
- Complejo cloro Complejo hidruro Compuesto bencénico Control cinético Ligando orgánico Estudio experimental Mecanismo reacción Paladio Complejo Fosfina terciaria Radical libre orgánico Reacción molécula radical Transferencia hidruro Metal transición Complejo Platinoide Complejo
- Classification
- Pascal
- 001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03B Reactivity and mechanisms / 001C03B04 Free radicals chemistry
- Discipline
- Organic chemistry
- Origin
- Inist-CNRS
- Database
- PASCAL
- INIST identifier
- 13934496
Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS
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DOI
10.1021/ja0271126 
https://dx.doi.org/10.1021/ja0271126
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