Stereoselective formation of inverted housane in the denitrogenation of the diazenyl diradical photolytically derived from a stereolabeled diazabicyclo[2,2,1]hept-2-ene with bridgehead substituents as a function of solvent- and temperature-varied viscosity
- Author
- ADAM, Waldemar1 ; MARTI, Vicente1 ; SAHIN, Coskun1 ; TROFIMOV, Alexei V1 2
[1] Institute of Organic Chemistry, University of Würzburg, Am Hubland, 97074 Würzburg, Germany
[2] Institute of Biochemical Physics, United Institute of Chemical Physics, Russian Academy of Sciences, ul. Kosygina 4, Moscow 117977, Russian Federation - Source
Chemical physics letters. 2001, Vol 340, Num 1-2, pp 26-32 ; ref : 25 ref
- CODEN
- CHPLBC
- ISSN
- 0009-2614
- Scientific domain
- General chemistry, physical chemistry; Atomic molecular physics; Condensed state physics
- Publisher
- Elsevier Science, Amsterdam
- Publication country
- Netherlands
- Document type
- Article
- Language
- Russian
- Keyword (fr)
- Composé azoïque Composé bicyclique Désazotation Effet milieu Effet solvant Effet température Hétérocycle azote Inversion conformation Mécanisme radicalaire Mécanisme réaction Phase liquide Photolyse UV Photolyse laser Stéréosélectivité Synthèse chimique Viscosité 2,3-Diazabicyclo[2.2.1]hept-2-ène(4,7-diméthyl-1-éthyl) Bicyclo[2.1.0]pentane1,5-diméthyl-4-éthyl Housane dérivé
- Keyword (en)
- Azo compound Bicyclic compound Denitrogenation Medium effect Solvent effect Temperature effect Nitrogen heterocycle Conformation inversion Radical mechanism Reaction mechanism Liquid phase Ultraviolet photolysis Laser photolysis Stereoselectivity Chemical synthesis Viscosity
- Keyword (es)
- Compuesto azoico Compuesto bicíclico Desazotación Efecto medio Efecto solvente Efecto temperatura Heterociclo nitrógeno Inversión conformación Mecanismo radicalar Mecanismo reacción Fase líquida Fotolisis UV Fotolisis laser Estereoselectividad Síntesis química Viscosidad
- Classification
- Pascal
- 001 Exact sciences and technology / 001C Chemistry / 001C01 General and physical chemistry / 001C01F Physical chemistry of induced reactions (with radiations, particles and ultrasonics) / 001C01F01 Photochemistry
- Pascal
- 001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03C Preparations and properties / 001C03C05 Alicyclic compounds, terpenoids, prostaglandins, steroids / 001C03C05A Alicyclic compounds
- Discipline
- General chemistry and physical chemistry Organic chemistry
- Origin
- Inist-CNRS
- Database
- PASCAL
- INIST identifier
- 14089293
Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS
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DOI
10.1016/S0009-2614(01)00355-4 
https://dx.doi.org/10.1016/S0009-2614(01)00355-4
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