Stereocontrol at the steady state in radical cyclizations of acyclic dihalides
- Author
- STALINSKI, Krzysztof1 ; CURRAN, Dennis P1
[1] Department of Chemistry, University of Pittsburgh, Pittsburgh, Pennsylvania 15260, United States - Source
Journal of organic chemistry. 2002, Vol 67, Num 9, pp 2982-2988
- CODEN
- JOCEAH
- ISSN
- 0022-3263
- Scientific domain
- Biochemistry, molecular biology, biophysics; Organic chemistry
- Publisher
- American Chemical Society, Washington, DC
- Publication country
- United States
- Document type
- Article
- Language
- English
- Keyword (fr)
- Cinétique Composé acétylénique Constante vitesse Cyclisation Effet substituant Effet température Halogène Composé organique Intermédiaire réaction Modèle cinétique Réaction radicalaire Réduction chimique Stéréosélectivité Synthèse organique Benzène(2-méthyl-4-méthylènecyclopentyl) Hex-1-yne(6-bromo-5-bromométhyl-4-phényl) Hex-1-yne(6-iodo-5-iodométhyl-4-phényl) Modèle Beckwith-Houk Stannane(triphényl)
- Keyword (en)
- Kinetics Acetylenic compound Rate constant Cyclization Substituent effect Temperature effect Halogen Organic compounds Reaction intermediate Kinetic model Free radical reaction Chemical reduction Stereoselectivity Organic synthesis
- Keyword (es)
- Cinética Compuesto acetilénico Constante velocidad Ciclización Efecto sustituyente Efecto temperatura Halógeno Compuesto orgánico Intermediario reacción Modelo cinético Reacción radicalar Reducción química Estereoselectividad Síntesis orgánica
- Classification
- Pascal
- 001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03B Reactivity and mechanisms / 001C03B04 Free radicals chemistry
- Discipline
- Organic chemistry
- Origin
- Inist-CNRS
- Database
- PASCAL
- INIST identifier
- 14189648
Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS
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DOI
10.1021/jo011056u 
https://dx.doi.org/10.1021/jo011056u
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