Mechanism of cis-enamide formation from N-(α-silyl)allyl amides: Synthetic potential of stepwise dyotropic rearrangements
- Author
- XIYUN ZHANG1 ; HOUK, K. N1 ; SONGNIAN LIN2 ; DANISHEFSKY, Samuel J2
[1] Department of Chemistry and Biochemistry, University of California, Los Angeles, California 90095, United States
[2] Department of Chemistry, Columbia University, New York, New York 10027, United States - Source
Journal of the American Chemical Society. 2003, Vol 125, Num 17, pp 5111-5114, 4 p ; ref : 11 ref
- CODEN
- JACSAT
- ISSN
- 0002-7863
- Scientific domain
- Biochemistry, molecular biology, biophysics; Chemistry; Organic chemistry; Atomic molecular physics
- Publisher
- American Chemical Society, Washington, DC
- Publication country
- United States
- Document type
- Article
- Language
- English
- Keyword (fr)
- Amide organique Benzamide dérivé Composé benzénique Energie activation Etat transition Etude théorique Méthode Hartree Fock Méthode fonctionnelle densité Potentiel électrostatique Schéma réactionnel Stabilisation chimique Transposition chimique Benzamide(N-[α-silylallyl]) Réaction dyotrope
- Keyword (en)
- Organic amide Benzamide derivatives Benzenic compound Activation energy Transition state Theoretical study Hartree Fock method Density functional method Electrostatic potential Reaction path Chemical stabilization Chemical rearrangement
- Keyword (es)
- Amida Benzamida derivado Compuesto bencénico Energía activación Estado transitorio Estudio teórico Método Hartree Fock Potencial electrostático Esquema reacciones Estabilización química Transposición química
- Classification
- Pascal
- 001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03B Reactivity and mechanisms / 001C03B02 Kinetics and mechanisms
- Discipline
- Organic chemistry
- Origin
- Inist-CNRS
- Database
- PASCAL
- INIST identifier
- 14737435
Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS
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DOI
10.1021/ja029576+ 
https://dx.doi.org/10.1021/ja029576+
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