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Mechanism of cis-enamide formation from N-(α-silyl)allyl amides: Synthetic potential of stepwise dyotropic rearrangements

Author
XIYUN ZHANG1 ; HOUK, K. N1 ; SONGNIAN LIN2 ; DANISHEFSKY, Samuel J2
[1] Department of Chemistry and Biochemistry, University of California, Los Angeles, California 90095, United States
[2] Department of Chemistry, Columbia University, New York, New York 10027, United States
Source

Journal of the American Chemical Society. 2003, Vol 125, Num 17, pp 5111-5114, 4 p ; ref : 11 ref

CODEN
JACSAT
ISSN
0002-7863
Scientific domain
Biochemistry, molecular biology, biophysics; Chemistry; Organic chemistry; Atomic molecular physics
Publisher
American Chemical Society, Washington, DC
Publication country
United States
Document type
Article
Language
English
Keyword (fr)
Amide organique Benzamide dérivé Composé benzénique Energie activation Etat transition Etude théorique Méthode Hartree Fock Méthode fonctionnelle densité Potentiel électrostatique Schéma réactionnel Stabilisation chimique Transposition chimique Benzamide(N-[α-silylallyl]) Réaction dyotrope
Keyword (en)
Organic amide Benzamide derivatives Benzenic compound Activation energy Transition state Theoretical study Hartree Fock method Density functional method Electrostatic potential Reaction path Chemical stabilization Chemical rearrangement
Keyword (es)
Amida Benzamida derivado Compuesto bencénico Energía activación Estado transitorio Estudio teórico Método Hartree Fock Potencial electrostático Esquema reacciones Estabilización química Transposición química
Classification
Pascal
001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03B Reactivity and mechanisms / 001C03B02 Kinetics and mechanisms

Discipline
Organic chemistry
Origin
Inist-CNRS
Database
PASCAL
INIST identifier
14737435

Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS

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