Metallacarbenes from diazoalkanes: An experimental and computational study of the reaction mechanism
- Author
- COHEN, Revital1 ; RYBTCHINSKI, Boris1 ; GANDELMAN, Mark1 ; ROZENBERG, Haim1 ; MARTIN, Jan M. L1 ; MILSTEIN, David1
[1] Department of Organic Chemistry, The Weizmann Institute of Science, 76100 Rehovot, Israel - Source
Journal of the American Chemical Society. 2003, Vol 125, Num 21, pp 6532-6546, 15 p
- CODEN
- JACSAT
- ISSN
- 0002-7863
- Scientific domain
- Biochemistry, molecular biology, biophysics; Chemistry; Organic chemistry; Atomic molecular physics
- Publisher
- American Chemical Society, Washington, DC
- Publication country
- United States
- Document type
- Article
- Language
- English
- Keyword (fr)
- Azote 15 Calcul ab initio Carbone 13 Composé diazoïque Coordinat organique Corrélation hétéronucléaire Etat transition Etude expérimentale Etude théorique Méthode fonctionnelle densité Paramètre thermodynamique Phosphore 31 Rhodium Complexe Réaction thermique Schéma réactionnel Spectrométrie 2 dimensions Spectrométrie RMN Structure moléculaire Surface énergie potentielle Benzène(1,3-bis[(diisopropylphosphino)méthyl]) Benzène(1-[diéthylamino]méthyl-3-[di-t-butylphosphino]méthyl) Méthane(diazo phényl) Métal transition Complexe Platinoïde Complexe
- Keyword (en)
- Nitrogen 15 Ab initio calculations Carbon 13 Diazo compound Organic ligand Heteronuclear correlation Transition state Experimental study Theoretical study Density functional method Thermodynamic parameter Phosphorus 31 Rhodium Complexes Thermal reaction Reaction path Two dimension spectrometry NMR spectrometry Molecular structure Potential energy surfaces Transition metal Complexes Platinoid Complexes
- Keyword (es)
- Compuesto diazoico Ligando orgánico Correlación heteronuclear Estado transitorio Estudio experimental Estudio teórico Parámetro termodinámico Rodio Complejo Reacción térmica Esquema reacciones Espectrometría bidimensional Espectrometría RMN Estructura molecular Metal transición Complejo Platinoide Complejo
- Classification
- Pascal
- 001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03B Reactivity and mechanisms / 001C03B02 Kinetics and mechanisms
- Discipline
- Organic chemistry
- Origin
- Inist-CNRS
- Database
- PASCAL
- INIST identifier
- 14830028
Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS
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DOI
10.1021/ja028923c 
https://dx.doi.org/10.1021/ja028923c
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