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Determination of the number of active centers and of the propagation rate constant for ethylene polymerization on supported Ni-containing catalysts by using 14CO

Author
BUKATOV, G. D1 ; GONCHAROV, V. S1 ; PANCHENKO, V. N1 ; ZAKHAROV, V. A1
[1] Boreskov Institute of Catalysis, Novosibirsk 630090, Russian Federation
Source

Macromolecular chemistry and physics (Print). 1998, Vol 199, Num 11, pp 2473-2476 ; ref : 5 ref

ISSN
1022-1352
Scientific domain
Polymers, paint and wood industries
Publisher
Wiley, Weinheim
Publication country
Germany
Document type
Article
Language
Russian
Keyword (fr)
Carbone monoxyde Catalyseur sur support Centre actif Cinétique Composé marqué Constante vitesse Ethylène polymère Etude expérimentale Inhibition réaction Magnésium Hydrure Métallocycle Méthode étude Nickel Composé organique Nickel complexe Phosphine tertiaire Polymérisation catalyseur complexe Propagation réaction Silice Carbone 14 Oléfine polymère
Keyword (en)
Carbon monoxide Supported catalyst Active center Kinetics Labelled compound Rate constant Polyethylene Experimental study Reaction inhibition Magnesium Hydrides Metallocycle Investigation method Nickel Organic compounds Nickel complex Tertiary phosphine Complex catalyst polymerization Reaction propagation Silica Olefin polymer
Keyword (es)
Carbono monóxido Catalizador sobre soporte Centro activo Cinética Compuesto marcado Constante velocidad Etileno polímero Estudio experimental Inhibición reacción Magnesio Hidruro Metalociclo Método estudio Niquel Compuesto orgánico Níquel complejo Fosfina terciaria Polimerización catalizador complejo Propagación reacción Sílice Olefina polímero
Classification
Pascal
001 Exact sciences and technology / 001D Applied sciences / 001D09 Physicochemistry of polymers / 001D09D Organic polymers / 001D09D02 Preparation, kinetics, thermodynamics, mechanism and catalysts / 001D09D02B Polymerization

Discipline
Physical chemistry of polymers
Origin
Inist-CNRS
Database
PASCAL
INIST identifier
1579889

Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS

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