Theoretical analysis of lewis basicity based on local electron-donating ability. Origin of basic strength of cyclic amines
- Author
- OHWADA, Tomohiko1 ; HIRAO, Hajime1 ; OGAWA, Atsushi2
[1] Graduate School of Pharmaceutical Sciences, The University of Tokyo, Tokyo 113-0033, Japan
[2] Division of Molecular Engineering, Kyoto University, Kyoto 606-8501, Japan - Source
Journal of organic chemistry. 2004, Vol 69, Num 22, pp 7486-7494, 9 p
- CODEN
- JOCEAH
- ISSN
- 0022-3263
- Scientific domain
- Biochemistry, molecular biology, biophysics; Organic chemistry
- Publisher
- American Chemical Society, Washington, DC
- Publication country
- United States
- Document type
- Article
- Language
- English
- Keyword (fr)
- Affinité protonique Amine Angle liaison Aziridine dérivé Azétidine dérivé Base Lewis Basicité Composé cyclique Donneur électron Etude expérimentale Etude théorique Hétérocycle azote Niveau énergie Orbitale hybride Phase gazeuse Pipéridine dérivé Pyrrolidine dérivé
- Keyword (en)
- Proton affinity Amine Bond angle Aziridine derivatives Azetidine derivatives Lewis base Alkalinity Cyclic compound Electron donor Experimental study Theoretical study Nitrogen heterocycle Energy level Hybrid orbital Gas phase Piperidine derivatives Pyrrolidine derivatives
- Keyword (es)
- Afinidad protónica Amina Angulo enlace Base Lewis Alcalinidad Compuesto cíclico Donador electrón Estudio experimental Estudio teórico Heterociclo nitrógeno Nivel energía Orbital híbrido Fase gaseosa Piperidina derivado
- Classification
- Pascal
- 001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03C Preparations and properties / 001C03C06 Heterocyclic compounds / 001C03C06B Heterocyclic compounds with only one n hetero atom and condensed derivatives
- Discipline
- Organic chemistry
- Origin
- Inist-CNRS
- Database
- PASCAL
- INIST identifier
- 16219202
Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS
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DOI
10.1021/jo0486589 
https://dx.doi.org/10.1021/jo0486589
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