New C-C coupling reaction of Cyclic nitronates with carbon nucleophiles. Umpolung of the conventional reactivity of nitronates
- Author
- SMIRNOV, Vladimir O1 ; IOFFE, Sema L1 ; TISHKOV, Alexander A1 ; KHOMUTOVA, Yulia A1 ; NESTEROV, Ivan D2 ; ANTIPIN, Michael Yu2 ; SMIT, William A1 ; TARTAKOVSKY, Vladimir A1
[1] N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Leninsky Prospect 47, 119991 Moscow, Russian Federation
[2] Russian Federation, and A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilov Street 28, 119991 Moscow, Russian Federation - Source
Journal of organic chemistry. 2004, Vol 69, Num 24, pp 8485-8488, 4 p
- CODEN
- JOCEAH
- ISSN
- 0022-3263
- Scientific domain
- Biochemistry, molecular biology, biophysics; Organic chemistry
- Publisher
- American Chemical Society, Washington, DC
- Publication country
- United States
- Document type
- Article
- Language
- Russian
- Keyword (fr)
- Acétal Catalyse homogène Composé éthylénique Copulation chimique Cycle 6 chaînons Diastéréosélectivité Etude expérimentale Hétérocycle oxygène azote Iminium composé Intermédiaire réaction Nitronate Réaction catalytique Réaction nucléophile Spectrométrie RMN 1,2-Oxazine dérivé Alc-2-énal dialkylacétal
- Keyword (en)
- Acetal Homogeneous catalysis Ethylenic compound Chemical coupling Six membered ring Diastereoselectivity Experimental study Oxygen nitrogen heterocycle Iminium compounds Reaction intermediate Nitronate Catalytic reaction Nucleophilic reaction NMR spectrometry
- Keyword (es)
- Acetal Catálisis homogénea Compuesto etilénico Copulación química Ciclo 6 eslabones Diastereoselectividad Estudio experimental Heterociclo oxígeno nitrógeno Iminio compuesto Intermediario reacción Nitronato Reacción catalítica Reacción nucléofila Espectrometría RMN
- Classification
- Pascal
- 001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03B Reactivity and mechanisms / 001C03B02 Kinetics and mechanisms
- Discipline
- Organic chemistry
- Origin
- Inist-CNRS
- Database
- PASCAL
- INIST identifier
- 16308222
Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS
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DOI
10.1021/jo048944k 
https://dx.doi.org/10.1021/jo048944k
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