Propylene-styrene multiblock copolymers: Evidence for monomer enchainment via opposite insertion regiochemistry by a single-site catalyst
- Author
- CAPACCHIONE, Carmine1 ; DE CARLO, Francesco1 ; ZANNONI, Carla2 ; OKUDA, Jun3 ; PROTO, Antonio1
[1] Department of Chemistry, University of Salerno, via S. Allende, 84081 Baronissi (SA), Italy
[2] Polimeri Europa-Istituto Donegani, via Fauser, 4, 28100 Novara, Italy
[3] Institut fur Anorganische Chemie, Aachen University of Technology (RWTH), Prof.-Pirlet-Strasse, 1, 52056 Aachen, Germany - Source
Macromolecules. 2004, Vol 37, Num 24, pp 8918-8922, 5 p
- CODEN
- MAMOBX
- ISSN
- 0024-9297
- Scientific domain
- Polymers, paint and wood industries
- Publisher
- American Chemical Society, Washington, DC
- Publication country
- United States
- Document type
- Article
- Language
- English
- Keyword (fr)
- Activité catalytique Catalyseur complexe Complexe aryloxy Complexe chloro Copolymère multiséquencé Etude expérimentale Microstructure Polymère isotactique Polymérisation catalyseur complexe Polymérisation stéréospécifique Propène copolymère Propène polymère Styrène copolymère Stéréospécificité Tacticité Titane complexe Aluminoxane(méthyl) Catalyseur site unique Oléfine polymère Structure moléculaire
- Keyword (en)
- Catalyst activity Complex catalyst Aryloxy complex Chloro complex Multiblock copolymer Experimental study Microstructure Isotactic polymer Complex catalyst polymerization Stereospecific polymerization Propylene copolymer Propylene polymer Styrene copolymer Stereospecificity Tacticity Titanium complex Olefin polymer Molecular structure
- Keyword (es)
- Actividad catalítica Catalizador complejo Complejo ariloxi Complejo cloro Copolímero multisecuencia Estudio experimental Microestructura Polímero isotáctico Polimerización catalizador complejo Polimerización estereoespecífica Propeno copolímero Propeno polímero Estireno copolímero Estereoespecificidad Tacticidad Titanio complejo Olefina polímero Estructura molecular
- Classification
- Pascal
- 001 Exact sciences and technology / 001D Applied sciences / 001D09 Physicochemistry of polymers / 001D09D Organic polymers / 001D09D02 Preparation, kinetics, thermodynamics, mechanism and catalysts / 001D09D02C Copolymerization
- Discipline
- Physical chemistry of polymers
- Origin
- Inist-CNRS
- Database
- PASCAL
- INIST identifier
- 16308721
Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS
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DOI
10.1021/ma048213m 
https://dx.doi.org/10.1021/ma048213m
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