On the dichotomic behavior of the Z-2,4-dinitrophenylhydrazone of 5-Amino-3-benzoyl-1,2,4-oxadiazole with acids in toluene and in dioxane/water: Rearrangement versus hydrolysis
- Author
- D'ANNA, Francesca1 ; FRENNA, Vincenzo1 ; MACALUSO, Gabriella1 ; MORGANTI, Stefano2 ; NITTI, Patrizia3 ; PACE, Vitalba1 ; SPINELLI, Domenico2 ; SPISANI, Raffaella2
[1] Dipartimento di Chimica Organica E. Paternò, Università degli Studi di Palermo, Viale delle Scienze, Parco d'Orleans 2, 90128 Palermo, Italy
[2] Dipartimento di Chimica Organica A. Mangini, University degli Studi di Bologna, Via San Donato 15, 40127 Bologna, Italy
[3] Dipartimento di Scienze Chimiche, Università degli Studi di Trieste, Via Licio Giorgieri 1, 34127 Trieste, Italy - Source
Journal of organic chemistry. 2004, Vol 69, Num 25, pp 8718-8722, 5 p
- CODEN
- JOCEAH
- ISSN
- 0022-3263
- Scientific domain
- Biochemistry, molecular biology, biophysics; Organic chemistry
- Publisher
- American Chemical Society, Washington, DC
- Publication country
- United States
- Document type
- Article
- Language
- English
- Keyword (fr)
- Catalyse acide Constante vitesse Cycle 5 chaînons Etude expérimentale Hydrazone Hétérocycle oxygène azote Mécanisme réaction Oxadiazole dérivé Paramètre cinétique Réaction catalytique Solvant organique Transposition chimique 1,2,4-Oxadiazole-3-carbaldéhyde(5-amino-3-benzoyl) 2,4-dinitrophénylhydrazone 1,2,4-Oxadiazole-3-carbaldéhyde(5-amino-3-benzoyl) phénylhydrazone Acétique acide(trichloro)
- Keyword (en)
- Acid catalysis Rate constant Five membered ring Experimental study Hydrazone Oxygen nitrogen heterocycle Reaction mechanism Oxadiazole derivatives Kinetic parameter Catalytic reaction Organic solvent Chemical rearrangement
- Keyword (es)
- Catálisis ácida Constante velocidad Ciclo 5 eslabones Estudio experimental Hidrazona Heterociclo oxígeno nitrógeno Mecanismo reacción Oxadiazol derivado Parámetro cinético Reacción catalítica Solvente orgánico Transposición química
- Classification
- Pascal
- 001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03B Reactivity and mechanisms / 001C03B02 Kinetics and mechanisms
- Discipline
- Organic chemistry
- Origin
- Inist-CNRS
- Database
- PASCAL
- INIST identifier
- 16322894
Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS
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DOI
10.1021/jo048803i 
https://dx.doi.org/10.1021/jo048803i
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