Kinetics of self-decomposition and hydrogen atom transfer reactions of substituted phthalimide N-oxyl radicals in acetic acid
- Author
- YANG CAI1 ; KOSHINO, Nobuyoshi1 ; SAHA, Basudeb1 ; ESPENSON, James H1
[1] Ames Laboratory and Department of Chemistry, Iowa State University of Science and Technology, Ames, Iowa 50011, United States - Source
Journal of organic chemistry. 2005, Vol 70, Num 1, pp 238-243, 6 p ; ref : 25 ref
- CODEN
- JOCEAH
- ISSN
- 0022-3263
- Scientific domain
- Biochemistry, molecular biology, biophysics; Organic chemistry
- Publisher
- American Chemical Society, Washington, DC
- Publication country
- United States
- Document type
- Article
- Language
- English
- Keyword (fr)
- Composé aromatique Composé bicyclique Constante vitesse Décomposition chimique Effet isotopique cinétique Enlèvement hydrogène Etude expérimentale Hétérocycle azote Imide Paramètre activation Paramètre cinétique Radical libre organique Réaction transfert Spectrométrie UV visible Transfert hydrogène Phtalimide-2-oxyle
- Keyword (en)
- Aromatic compound Bicyclic compound Rate constant Chemical decomposition Kinetic isotope effect Hydrogen abstraction Experimental study Nitrogen heterocycle Imide Activation parameter Kinetic parameter Organic free radical Transfer reaction Ultraviolet visible spectrometry Hydrogen transfer
- Keyword (es)
- Compuesto aromático Compuesto bicíclico Constante velocidad Descomposición química Efecto isotópico cinético Abstracción hidrógeno Estudio experimental Heterociclo nitrógeno Imida Parámetro activación Parámetro cinético Radical libre orgánico Reacción transferencia Espectrometría UV visible Transferencia hidrógeno
- Classification
- Pascal
- 001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03B Reactivity and mechanisms / 001C03B04 Free radicals chemistry
- Discipline
- Organic chemistry
- Origin
- Inist-CNRS
- Database
- PASCAL
- INIST identifier
- 16440112
Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS
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DOI
10.1021/jo048418t 
https://dx.doi.org/10.1021/jo048418t
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