Study of the thermal elimination and degradation processes of n-alkylsulfinyl-PPVv and -OC1C10-PPV precursor polymers with in situ spectroscopic techniques
- Author
- KESTERS, E1 ; VANDERZANDE, T. D1 2 ; LUTSEN, L2 ; PENXTEN, H1 ; CARLEER, R1
[1] Division Chemistry, IMO, Limburgs Universitair Centrum, Universitaire Campus Bld. D, 3590 Diepenbeek, Belgium
[2] Division IMOMEC, IMEC, Universitaire Campus Bld. D, 3590 Diepenbeek, Belgium - Source
Macromolecules. 2005, Vol 38, Num 4, pp 1141-1147, 7 p ; ref : 42 ref
- CODEN
- MAMOBX
- ISSN
- 0024-9297
- Scientific domain
- Polymers, paint and wood industries
- Publisher
- American Chemical Society, Washington, DC
- Publication country
- United States
- Document type
- Article
- Language
- English
- Keyword (fr)
- Acide sulfénique Cinétique Condition non isotherme Elimination Energie activation Etude expérimentale Modification chimique Phénylène dérivé polymère Phénylènevinylène dérivé polymère Phénylènevinylène polymère Polymère conjugué Polymère fonctionnel Polymère soufre Précurseur Réaction thermique Réactivité chimique Stabilité thermique Phénylènevinylène(2-[3,7-diméthyloctyloxy]-5-méthoxy) polymère Phénylèneéthylène(butylsulfinyl) polymère Phénylèneéthylène(octylsulfinyl) polymère
- Keyword (en)
- Sulfenic acid Kinetics Non isothermal condition Elimination Activation energy Experimental study Chemical modification Phenylene derivative polymer Phenylenevinylene derivative polymer Phenylenevinylene polymer Conjugated polymer Functional polymer Sulfur containing polymer Precursor Thermal reaction Chemical reactivity Thermal stability
- Keyword (es)
- Acido sulfénico Cinética Condición no isoterma Eliminación Energía activación Estudio experimental Modificación química Fenileno derivado polímero Fenilenovinileno derivado polimero Fenilenovinileno polímero Polímero conjugado Polímero funcional Polímero azufre Precursor Reacción térmica Reactividad química Estabilidad térmica
- Classification
- Pascal
- 001 Exact sciences and technology / 001D Applied sciences / 001D09 Physicochemistry of polymers / 001D09D Organic polymers / 001D09D03 Chemical reactions and properties / 001D09D03A Chemical modifications
- Discipline
- Physical chemistry of polymers
- Origin
- Inist-CNRS
- Database
- PASCAL
- INIST identifier
- 16535609
Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS
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DOI
10.1021/ma049545u 
https://dx.doi.org/10.1021/ma049545u
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