Steric and electronic properties of N-heterocyclic carbenes (NHC) : A detailed study on their interaction with Ni(CO)4
- Author
- DORTA, Reto; STEVENS, Edwin D; SCOTT, Natalie M; COSTABILE, Chiara; CAVALLO, Luigi; HOFF, Carl D1 ; NOLAN, Steven P
Department of Chemistry, University of New Orleans, New Orleans, Louisiana 70148, United States
Dipartimento di Chimica, Università di Salerno, Baronissi, SA 84081, Italy
[1] Department of Chemistry, University of Miami, Coral Gables, Florida 33124, United States - Source
Journal of the American Chemical Society. 2005, Vol 127, Num 8, pp 2485-2495, 11 p ; ref : 41 ref
- CODEN
- JACSAT
- ISSN
- 0002-7863
- Scientific domain
- Biochemistry, molecular biology, biophysics; Chemistry; Organic chemistry; Atomic molecular physics
- Publisher
- American Chemical Society, Washington, DC
- Publication country
- United States
- Document type
- Article
- Language
- English
- Keyword (fr)
- Cycle 5 chaînons Diradical libre organique Effet stérique Effet substituant Etude expérimentale Etude théorique Hétérocycle azote Imidazole dérivé Interaction moléculaire Interaction électronique Méthode dynamique moléculaire Méthode fonctionnelle densité Nickel Carbonyle Complexe Paramètre thermodynamique Réactivité chimique Spectrométrie IR Spectrométrie RMN Métal transition Carbonyle Complexe
- Keyword (en)
- Five membered ring Organic free biradical Steric effect Substituent effect Experimental study Theoretical study Nitrogen heterocycle Imidazole derivatives Molecular interaction Electron interaction Molecular dynamics method Density functional method Nickel Carbonyl Complexes Thermodynamic parameter Chemical reactivity Infrared spectrometry NMR spectrometry Transition metal Carbonyl Complexes
- Keyword (es)
- Ciclo 5 eslabones Dirradical libre orgánico Efecto estérico Efecto sustituyente Estudio experimental Estudio teórico Heterociclo nitrógeno Imidazol derivado Interacción molecular Interacción electrónica Método dinámico molecular Niquel Carbonilo Complejo Parámetro termodinámico Reactividad química Espectrometría IR Espectrometría RMN Metal transición Carbonilo Complejo
- Classification
- Pascal
- 001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03B Reactivity and mechanisms / 001C03B04 Free radicals chemistry
- Discipline
- Organic chemistry
- Origin
- Inist-CNRS
- Database
- PASCAL
- INIST identifier
- 16578814
Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS
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DOI
10.1021/ja0438821 
https://dx.doi.org/10.1021/ja0438821
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