Superacidifiers : Assessing the activation and the mode of charge transmission of the extraordinary electron-withdrawing SO2CF3 and S(O)(=NSO2CF3)CF3 substituents in carbanion stabilization
- Author
- TERRIER, Francois; MAGNIER, Emmanuel; KIZILIAN, Elyane; WAKSELMAN, Claude; BUNCEL, Erwin
Department of Chemistry, Queen's University, Kingston, Ontario, K7L 3N6, Canada
Laboratoire SIRCOB, UMR 8086, Institut Lavoisier-Franklin, Université de Versailles, 45, Avenue des Etats-Unis, 78035 Versailles, France - Source
Journal of the American Chemical Society. 2005, Vol 127, Num 15, pp 5563-5571, 9 p ; ref : 44 ref
- CODEN
- JACSAT
- ISSN
- 0002-7863
- Scientific domain
- Biochemistry, molecular biology, biophysics; Chemistry; Organic chemistry; Atomic molecular physics
- Publisher
- American Chemical Society, Washington, DC
- Publication country
- United States
- Document type
- Article
- Language
- English
- Keyword (fr)
- Composé benzénique Constante acidité Contrôle cinétique Contrôle thermodynamique Effet substituant Etude expérimentale Propriété chimique Solution aqueuse Solvant organique Spectrométrie RMN Spectrométrie UV visible Sulfoximide Benzilique acide dérivé
- Keyword (en)
- Benzenic compound Acidity constant Kinetic control Thermodynamic control Substituent effect Experimental study Chemical properties Aqueous solution Organic solvent NMR spectrometry Ultraviolet visible spectrometry Sulfoximide
- Keyword (es)
- Compuesto bencénico Constante acidez Control cinético Control termodinámico Efecto sustituyente Estudio experimental Propiedad química Solución acuosa Solvente orgánico Espectrometría RMN Espectrometría UV visible Sulfoximida
- Classification
- Pascal
- 001 Exact sciences and technology / 001C Chemistry / 001C01 General and physical chemistry / 001C01B Solutions / 001C01B02 Solution properties
- Discipline
- General chemistry and physical chemistry
- Origin
- Inist-CNRS
- Database
- PASCAL
- INIST identifier
- 16698657
Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS
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DOI
10.1021/ja0436291 
https://dx.doi.org/10.1021/ja0436291
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