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Observations on the reactivity of thiyl radicals derived from 3,6-epidithiodiketopiperazine-2,5-diones and related congeners

Author
HILTON, S. T1 ; MOTHERWELL, W. B1 ; POTIER, P2 ; PRADET, C1 ; SELWOOD, D. L3
[1] Chemistry Department, University College London, Christopher Ingold Laboratories, 20 Gordon Street, London WC1H OAJ, United Kingdom
[2] Institut de Chimie des Substances Naturelles, CNRS, 91198 Gif-sur-Yvette, France
[3] The Wolfson Institute for Biomedical Research, University College London, The Cruciform Building, Gower Street, London WC1E 6BT, United Kingdom
Source

Bioorganic & medicinal chemistry letters (Print). 2005, Vol 15, Num 9, pp 2239-2242, 4 p

ISSN
0960-894X
Scientific domain
Biochemistry, molecular biology, biophysics; Pharmacology drugs
Publisher
Elsevier, Oxford
Publication country
United Kingdom
Document type
Article
Language
English
Author keyword
DNA cleavage Epidithiodiketopiperazines Mechanism Polarity reversal catalysis Thiyl radicals
Keyword (fr)
Cycle 6 chaînons Hydrosilylation Hétérocycle azote Lactame Lactone Mécanisme Racémisation Radical thiyle Réaction radicalaire Réactivité chimique Benzoïque acide(4-chloro) ester furfuryle Pyran-2-one(5,5-diméthyl-6-méthylène-perhydro)
Keyword (en)
Six membered ring Hydrosilylation Nitrogen heterocycle Lactam Lactone Mechanism Racemization Thiyl radicals Free radical reaction Chemical reactivity
Keyword (es)
Ciclo 6 eslabones Hidrosililación Heterociclo nitrógeno Lactamo Lactona Mecanismo Racemización Reacción radicalar Reactividad química
Classification
Pascal
001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03C Preparations and properties / 001C03C06 Heterocyclic compounds / 001C03C06C Heterocyclic compounds with several n hetero atoms in the same ring, in separated rings or in fused rings

Discipline
Organic chemistry
Origin
Inist-CNRS
Database
PASCAL
INIST identifier
16712664

Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS

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