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Organocatalytic asymmetric direct alkylation of α-diazoester via C-H bond cleavage

Author
URAGUCHI, Daisuke1 ; SORIMACHI, Keiichi1 ; TERADA, Masahiro1
[1] Department of Chemistry, Graduate School of Science, Tohoka University, Sendai 980-8578, Japan
Source

Journal of the American Chemical Society. 2005, Vol 127, Num 26, pp 9360-9361, 2 p ; ref : 15 ref

CODEN
JACSAT
ISSN
0002-7863
Scientific domain
Biochemistry, molecular biology, biophysics; Chemistry; Organic chemistry; Atomic molecular physics
Publisher
American Chemical Society, Washington, DC
Publication country
United States
Document type
Article
Language
English
Keyword (fr)
Activité catalytique Aldimine Catalyse homogène Composé diazoïque Enantiosélectivité Etude expérimentale Mécanisme réaction Réaction Friedel Crafts Réaction asymétrique Réaction catalytique Sélectivité catalyseur Acétique acide(diazo) ester éthyle Arènecarbaldéhyde aroylimine Phosphorique acide dérivé
Keyword (en)
Catalyst activity Aldimine Homogeneous catalysis Diazo compound Enantioselectivity Experimental study Reaction mechanism Friedel Crafts reaction Asymmetric reaction Catalytic reaction Catalyst selectivity
Keyword (es)
Actividad catalítica Aldimina Catálisis homogénea Compuesto diazoico Enantioselectividad Estudio experimental Mecanismo reacción Reacción Friedel Crafts Reacción asimétrica Reacción catalítica Selectividad catalizador
Classification
Pascal
001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03B Reactivity and mechanisms / 001C03B02 Kinetics and mechanisms

Discipline
Organic chemistry
Origin
Inist-CNRS
Database
PASCAL
INIST identifier
16934058

Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS

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