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The structure of the homogeneous oxidation catalyst, Mn(II)(Br-1)x, in supercritical water : An X-ray absorption fine-structure study

Author
YONGSHENG CHEN1 ; FULTON, John L1 ; PARTENHEIMER, Walter2
[1] Chemical Sciences Division, Pacific Northwest National Laboratory, Richland, Washington 99352, United States
[2] Central Research and Development, E. I. DuPont de Nemours & Co. Inc., Experimental Station, Wilmington, Delaware 19880, United States
Source

Journal of the American Chemical Society. 2005, Vol 127, Num 40, pp 14085-14093, 9 p

CODEN
JACSAT
ISSN
0002-7863
Scientific domain
Biochemistry, molecular biology, biophysics; Chemistry; Organic chemistry; Atomic molecular physics
Publisher
American Chemical Society, Washington, DC
Publication country
United States
Document type
Article
Language
English
Keyword (fr)
Activité catalytique Catalyse homogène Composé benzénique Dégradation oxydante Etat supercritique Etude expérimentale Intermédiaire réaction Manganèse bromure Radical libre organique Réaction catalytique Réaction thermique Solution aqueuse Spectrométrie EXAFS Spectrométrie XANES p-Xylène Métal transition Composé
Keyword (en)
Catalyst activity Homogeneous catalysis Benzenic compound Oxidative degradation Supercritical state Experimental study Reaction intermediate Manganese bromide Organic free radical Catalytic reaction Thermal reaction Aqueous solution EXAFS spectrometry XANES spectrometry p-Xylene Transition metal Compounds
Keyword (es)
Actividad catalítica Catálisis homogénea Compuesto bencénico Degradación oxidante Estado supercrítico Estudio experimental Intermediario reacción Manganeso bromuro Radical libre orgánico Reacción catalítica Reacción térmica Solución acuosa Espectrometría EXAFS Espectrometría XANES p-Xileno Metal transición Compuesto
Classification
Pascal
001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03B Reactivity and mechanisms / 001C03B02 Kinetics and mechanisms

Discipline
Organic chemistry
Origin
Inist-CNRS
Database
PASCAL
INIST identifier
17184207

Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS

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