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Internally solvated cyclopentadienyllithium compounds : Structural integrity of the Cp-Li+ moiety. NMR, dynamics, X-ray crystallography, and calculations

Author
FRAENKEL, Gideon1 ; XIAO CHEN1 ; CHOW, Albert1 ; GALLUCCI, Judith C1 ; HUA LIU1
[1] Department of Chemistry, Ohio State University, Columbus, Ohio 43210, United States
Source

Journal of organic chemistry. 2005, Vol 70, Num 23, pp 9131-9138, 8 p ; ref : 21 ref

CODEN
JOCEAH
ISSN
0022-3263
Scientific domain
Biochemistry, molecular biology, biophysics; Organic chemistry
Publisher
American Chemical Society, Washington, DC
Publication country
United States
Document type
Article
Language
English
Keyword (fr)
Carbanion Carbone 13 Composé allylique Composé chiral Diffraction RX Déprotonation Enthalpie Etude expérimentale Etude théorique Ligand Lithium Composé organique Lithium complexe Méthode fonctionnelle densité Solvatation Spectrométrie RMN Structure moléculaire Stéréochimie Cyclopentadiène dérivé Lithium(butyl)
Keyword (en)
Carbanion Carbon 13 Allylic compound Chiral compound X ray diffraction Deprotonation Enthalpy Experimental study Theoretical study Ligand Lithium Organic compounds Lithium complex Density functional method Solvation NMR spectrometry Molecular structure Stereochemistry
Keyword (es)
Carbanión Compuesto alílico Compuesto quiral Difracción RX Desprotonación Entalpía Estudio experimental Estudio teórico Ligando Litio Compuesto orgánico Litio complejo Solvatación Espectrometría RMN Estructura molecular Estereoquímica
Classification
Pascal
001 Exact sciences and technology / 001C Chemistry / 001C02 Inorganic chemistry and origins of life / 001C02B Preparations and properties / 001C02B04 Coordination compounds

Discipline
Mineral chemistry and origin of life
Origin
Inist-CNRS
Database
PASCAL
INIST identifier
17256459

Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS

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