Regio- and stereoselective reactions of gem-difluorinated vinyloxiranes with heteronucleophiles
- Author
- UEKI, Hisanori1 ; KITAZUME, Tomoya1
[1] Graduate School of Bioscience and Bioengineering, Tokyo Institute of Technology, 4259 Nagatsuta-cho, Midori-ku, Yokohama 226-8501, Japan - Source
Journal of organic chemistry. 2005, Vol 70, Num 23, pp 9354-9363, 10 p ; ref : 24 ref
- CODEN
- JOCEAH
- ISSN
- 0022-3263
- Scientific domain
- Biochemistry, molecular biology, biophysics; Organic chemistry
- Publisher
- American Chemical Society, Washington, DC
- Publication country
- United States
- Document type
- Article
- Language
- English
- Keyword (fr)
- Acide Brönsted Acétique acide dérivé Alcool Composé allylique Composé vinylique Diastéréoisomère Epoxyde Fluor Composé organique Halogénation Hétérocycle oxygène Lithium bromure Magnésium bromure Milieu acide Mécanisme SN2' Oxirane dérivé Régiosélectivité Stéréochimie Stéréosélectivité Sélectivité Borane(trichloro)
- Keyword (en)
- Brönsted acid Acetic acid derivative Alcohol Allylic compound Vinylic compound Diastereomer Epoxide Fluorine Organic compounds Halogenation Oxygen heterocycle Lithium bromide Magnesium bromide Acid medium SN2' mechanism Oxirane derivatives Regioselectivity Stereochemistry Stereoselectivity Selectivity
- Keyword (es)
- Acido Bronsted Acético ácido derivado Alcohol Compuesto alílico Compuesto vinílico Diasteréomero Epóxido Fluor Compuesto orgánico Halogenación Heterociclo oxígeno Litio bromuro Magnesio bromuro Medio ácido Mecanismo SN2' Oxirano derivado Regioselectividad Estereoquímica Estereoselectividad Selectividad
- Classification
- Pascal
- 001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03C Preparations and properties / 001C03C02 Aliphatic compounds
- Discipline
- Organic chemistry
- Origin
- Inist-CNRS
- Database
- PASCAL
- INIST identifier
- 17256485
Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS
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DOI
10.1021/jo051468t 
https://dx.doi.org/10.1021/jo051468t
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