Significant proximity and cocatalyst effects in binuclear catalysis for olefin polymerization
- Author
- HONGBO LI1 ; STERN, Charlotte L1 ; MARKS, Tobin J1
[1] Department of Chemistry, Northwestern University, Evanston, Illinois 60208-3113, United States - Source
Macromolecules. 2005, Vol 38, Num 22, pp 9015-9027, 13 p
- CODEN
- MAMOBX
- ISSN
- 0024-9297
- Scientific domain
- Polymers, paint and wood industries
- Publisher
- American Chemical Society, Washington, DC
- Publication country
- United States
- Document type
- Article
- Language
- English
- Keyword (fr)
- Activité catalytique Catalyseur complexe Complexe dinucléaire Copolymère ramifié Copolymérisation catalyseur complexe Copolymérisation solution Effet proximité Effet solvant Effet stérique Ethylène copolymère Ethylène polymère Etude comparative Etude expérimentale Hexène copolymère Mécanisme réaction Polymère ramifié Polymérisation catalyseur complexe Polymérisation solution Silazane organique Solvant polaire Structure cristalline Synthèse chimique Transfert chaîne Zirconium Composé organique Zirconium complexe Aluminoxane(méthyl) Catalyseur géométrie contrainte Oléfine copolymère Oléfine polymère
- Keyword (en)
- Catalyst activity Complex catalyst Dinuclear complex Branched copolymer Complex catalyst copolymerization Solution copolymerization Proximity effect Solvent effect Steric effect Ethylene copolymer Polyethylene Comparative study Experimental study Hexene copolymer Reaction mechanism Branched polymer Complex catalyst polymerization Solution polymerization Organic silazane Polar solvent Crystalline structure Chemical synthesis Chain transfer Zirconium Organic compounds Zirconium complex Olefin copolymer Olefin polymer
- Keyword (es)
- Actividad catalítica Catalizador complejo Complejo dinuclear Copolímero ramificado Copolimerización catalizador complejo Copolimerización solución Efecto proximidad Efecto solvente Efecto estérico Etileno copolímero Etileno polímero Estudio comparativo Estudio experimental Hexeno copolímero Mecanismo reacción Polímero ramificado Polimerización catalizador complejo Polimerización solución Silazano orgánico Disolvente polar Estructura cristalina Síntesis química Transferencia en cadena Zirconio Compuesto orgánico Zirconio complejo Olefina copolímero Olefina polímero
- Classification
- Pascal
- 001 Exact sciences and technology / 001D Applied sciences / 001D09 Physicochemistry of polymers / 001D09D Organic polymers / 001D09D02 Preparation, kinetics, thermodynamics, mechanism and catalysts / 001D09D02B Polymerization
- Discipline
- Physical chemistry of polymers
- Origin
- Inist-CNRS
- Database
- PASCAL
- INIST identifier
- 17259563
Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS
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DOI
10.1021/ma050959c 
https://dx.doi.org/10.1021/ma050959c
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