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The somersault mechanism for the P-450 hydroxylation of hydrocarbons. The intervention of transient inverted metastable hydroperoxides

Author
BACH, Robert D1 ; DMITRENKO, Olga1
[1] Department of Chemistry and Biochemistry, University of Delaware, Newark, Delaware 19716, United States
Source

Journal of the American Chemical Society. 2006, Vol 128, Num 5, pp 1474-1488, 15 p ; ref : 32 ref

CODEN
JACSAT
ISSN
0002-7863
Scientific domain
Biochemistry, molecular biology, biophysics; Chemistry; Organic chemistry; Atomic molecular physics
Publisher
American Chemical Society, Washington, DC
Publication country
United States
Document type
Article
Language
English
Keyword (fr)
Catalyse enzymatique Cytochrome P450 Diradical libre organique Dégradation oxydante Etat transition Etude théorique Hydrocarbure Hydroperoxyde organique Hydroxylation Interaction configuration Intermédiaire réaction Isobutane Méthode fonctionnelle densité Paramètre thermodynamique Réaction catalytique Schéma réactionnel Surface énergie potentielle
Keyword (en)
Enzymatic catalysis Cytochrome P450 Organic free biradical Oxidative degradation Transition state Theoretical study Hydrocarbon Organic hydroperoxide Hydroxylation Configuration interaction Reaction intermediate Isobutane Density functional method Thermodynamic parameter Catalytic reaction Reaction path Potential energy surfaces
Keyword (es)
Catálisis enzimática Citocromo P450 Dirradical libre orgánico Degradación oxidante Estado transitorio Estudio teórico Hidrocarburo Hidroperóxido orgánico Hidroxilación Interacción configuración Intermediario reacción Isobutano Parámetro termodinámico Reacción catalítica Esquema reacciones
Classification
Pascal
002 Biological and medical sciences / 002A Fundamental and applied biological sciences. Psychology / 002A03 Molecular biophysics / 002A03E Physical chemistry in biology / 002A03E01 Mechanisms. Catalysis. Electron transfer. Models

Discipline
Molecular biophysics
Origin
Inist-CNRS
Database
PASCAL
INIST identifier
17719838

Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS

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