Intramolecularly dinuclear magnesium complex catalyzed copolymerization of cyclohexene oxide with CO2 under ambient CO2 pressure : Kinetics and mechanism
- Author
- YOULI XIAO1 ; ZHENG WANG1 ; KUILING DING1
[1] State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Road, Shanghai 200032, China - Source
Macromolecules. 2006, Vol 39, Num 1, pp 128-137, 10 p
- CODEN
- MAMOBX
- ISSN
- 0024-9297
- Scientific domain
- Polymers, paint and wood industries
- Publisher
- American Chemical Society, Washington, DC
- Publication country
- United States
- Document type
- Article
- Language
- English
- Keyword (fr)
- Activité catalytique Carbone dioxyde Catalyseur complexe Cinétique chimique Complexe aryloxy Complexe dinucléaire Condition opératoire modérée Copolymérisation alternée Copolymérisation catalyseur complexe Copolymérisation ouverture cycle Copolymérisation solution Effet substituant Epoxyde Etude expérimentale Magnésium complexe Mécanisme réaction Pression atmosphérique Structure cristalline Cyclohexène carbonate polymère
- Keyword (en)
- Catalyst activity Carbon dioxide Complex catalyst Chemical reaction kinetics Aryloxy complex Dinuclear complex Mild operating conditions Alternating copolymerization Complex catalyst copolymerization Ring opening copolymerization Solution copolymerization Substituent effect Epoxide Experimental study Magnesium complex Reaction mechanism Atmospheric pressure Crystalline structure
- Keyword (es)
- Actividad catalítica Carbono dióxido Catalizador complejo Cinética química Complejo ariloxi Complejo dinuclear Condición operatoria moderada Copolimerización alternada Copolimerización catalizador complejo Copolimerización abertura ciclo Copolimerización solución Efecto sustituyente Epóxido Estudio experimental Magnesio complejo Mecanismo reacción Presión atmosférica Estructura cristalina
- Classification
- Pascal
- 001 Exact sciences and technology / 001D Applied sciences / 001D09 Physicochemistry of polymers / 001D09D Organic polymers / 001D09D02 Preparation, kinetics, thermodynamics, mechanism and catalysts / 001D09D02C Copolymerization
- Discipline
- Physical chemistry of polymers
- Origin
- Inist-CNRS
- Database
- PASCAL
- INIST identifier
- 17728245
Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS
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DOI
10.1021/ma051859+ 
https://dx.doi.org/10.1021/ma051859+
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