Radical ring expansion reactions of methylenecyclopropane derivatives : A theoretical study
- Author
- ARDURA, Diego1 ; SORDO, Tomas L1
[1] Departamento de Química-Física y Analítica, Universidad de Oviedo, C/ Juliân Clavería, 8, 33006 Oviedo, Spain - Source
Journal of organic chemistry. 2006, Vol 71, Num 13, pp 4803-4809, 7 p ; ref : 18 ref
- CODEN
- JOCEAH
- ISSN
- 0022-3263
- Scientific domain
- Biochemistry, molecular biology, biophysics; Organic chemistry
- Publisher
- American Chemical Society, Washington, DC
- Publication country
- United States
- Document type
- Article
- Language
- English
- Keyword (fr)
- Agrandissement cycle Barrière énergie Composé éthylénique Contrôle thermodynamique Cyclopropane dérivé Effet solvant Energie libre Gibbs Etude expérimentale Etude théorique Méthode fonctionnelle densité Prédiction Radical libre organique Silane organique Solvatation Stéréoisomère endo Stéréoisomère exo Cyclopropane(méthylène)
- Keyword (en)
- Ring expansion Energy barrier Ethylenic compound Thermodynamic control Cyclopropane derivatives Solvent effect Gibbs free energy Experimental study Theoretical study Density functional method Prediction Organic free radical Organic silane Solvation Endo stereoisomer Exo stereoisomer
- Keyword (es)
- Expansión anillo Barrera energía Compuesto etilénico Control termodinámico Ciclopropano derivado Efecto solvente Energía libre Gibbs Estudio experimental Estudio teórico Predicción Radical libre orgánico Silano orgánico Solvatación Estereoisómero endo Estereoisómero exo
- Classification
- Pascal
- 001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03C Preparations and properties / 001C03C05 Alicyclic compounds, terpenoids, prostaglandins, steroids / 001C03C05A Alicyclic compounds
- Discipline
- Organic chemistry
- Origin
- Inist-CNRS
- Database
- PASCAL
- INIST identifier
- 17893575
Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS
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DOI
10.1021/jo0602625 
https://dx.doi.org/10.1021/jo0602625
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