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Reactivity and acid-base behavior of ring-methoxylated arylalkanoic acid radical cations and radical zwitterions in aqueous solution. Influence of structural effects and pH on the benzylic C-H deprotonation pathway

Author
BIETTI, Massimo1 ; CAPONE, Alberto1
[1] Dipartimento di Scienze e Tecnologie Chimiche, Università Tor Vergata, Via della Ricerca Scientifica 1, 00133 Rome, Italy
Source

Journal of organic chemistry. 2006, Vol 71, Num 14, pp 5260-5267, 8 p ; ref : 50 ref

CODEN
JOCEAH
ISSN
0022-3263
Scientific domain
Biochemistry, molecular biology, biophysics; Organic chemistry
Publisher
American Chemical Society, Washington, DC
Publication country
United States
Document type
Article
Language
English
Keyword (fr)
Acide carboxylique Acidité Chaîne latérale Cinétique Composé aromatique Composé benzylique Constante vitesse Décarboxylation Déprotonation Effet structure Equilibre acidobasique Fragmentation Ion amphotère Milieu acide Milieu basique Oxydation Radical libre cationique Radical libre organique Réactivité chimique Résolution temporelle Solution aqueuse Solution chimique Effet pH
Keyword (en)
Carboxylic acid Acidity Side chain Kinetics Aromatic compound Benzylic compound Rate constant Decarboxylation Deprotonation Structure effect Acid base balance Fragmentation Zwitterion Acid medium Basic medium Oxidation Radical cation Organic free radical Chemical reactivity Time resolution Aqueous solution Chemical solution
Keyword (es)
Acido carboxílico Acidez Cadena lateral Cinética Compuesto aromático Compuesto benzílico Constante velocidad Descarboxilación Desprotonación Efecto estructura Equilibrio acido-base Fragmentación Ión anfotérico Medio ácido Medio básico Oxidación Radical libre catiónico Radical libre orgánico Reactividad química Resolución temporal Solución acuosa Solución química
Classification
Pascal
001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03B Reactivity and mechanisms / 001C03B02 Kinetics and mechanisms

Discipline
Organic chemistry
Origin
Inist-CNRS
Database
PASCAL
INIST identifier
17933663

Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS

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