Rhodium-catalyzed intermolecular chelation controlled alkene and alkyne hydroacylation : Synthetic scope of β-S-substituted aldehyde substrates
- Author
- WILLIS, Michael C1 ; RANDELL-SLY, Helen E1 ; WOODWARD, Robert L1 ; MCNALLY, Steven J1 ; CURRIE, Gordon S2
[1] Department of Chemistry, University of Bath, Bath, BA2 7AY, United Kingdom
[2] AstraZeneca, Alderley Park, Macclesfield, Cheshire, SK10 4TG, United Kingdom - Source
Journal of organic chemistry. 2006, Vol 71, Num 14, pp 5291-5297, 7 p ; ref : 35 ref
- CODEN
- JOCEAH
- ISSN
- 0022-3263
- Scientific domain
- Biochemistry, molecular biology, biophysics; Organic chemistry
- Publisher
- American Chemical Society, Washington, DC
- Publication country
- United States
- Document type
- Article
- Language
- English
- Keyword (fr)
- Acylation Alcyne Alcène Aldéhyde Catalyseur Chélation Composé acétylénique Composé éthylénique Enone Ester Groupe fonctionnel Milieu neutre Rhodium Réaction catalytique Réaction intermoléculaire Régiosélectivité Stéréoisomère anti Sulfure organique Synthèse chimique Sélectivité Thioacétal Métal transition Platinoïde
- Keyword (en)
- Acylation Alkyne Alkene Aldehyde Catalyst Chelation Acetylenic compound Ethylenic compound Enone Ester Functional group Neutral medium Rhodium Catalytic reaction Intermolecular reaction Regioselectivity Anti stereoisomer Organic sulfide Chemical synthesis Selectivity Thioacetal Transition metal Platinoid
- Keyword (es)
- Acilación Alquino Alqueno Aldehído Catalizador Quelación Compuesto acetilénico Compuesto etilénico Enona Ester Grupo funcional Medio neutro Rodio Reacción catalítica Reacción intermolecular Regioselectividad Estereoisómero anti Sulfuro orgánico Síntesis química Selectividad Tioacetal Metal transición Platinoide
- Classification
- Pascal
- 001 Exact sciences and technology / 001C Chemistry / 001C01 General and physical chemistry / 001C01A Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry / 001C01A03 Catalysis / 001C01A03A Catalysts: preparations and properties
- Discipline
- General chemistry and physical chemistry Organic chemistry
- Origin
- Inist-CNRS
- Database
- PASCAL
- INIST identifier
- 17933667
Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS
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DOI
10.1021/jo060582o 
https://dx.doi.org/10.1021/jo060582o
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