Investigation of lipase-catalyzed ring-opening polymerizations of lactones with various ring sizes : Kinetic evaluation
- Author
- VAN DER MEE, Lars1 ; HELMICH, Floris1 ; DE BRUIJN, Robin1 ; VEKEMANS, Jef A. J. M1 ; PALMANS, Anja R. A1 ; MEIJER, E. W1
[1] Laboratory of Macromolecular and Organic Chemistry, Technische Universiteit Eindhoven, PO Box 513, 5600 MB Eindhoven, Netherlands - Source
Macromolecules. 2006, Vol 39, Num 15, pp 5021-5027, 7 p
- CODEN
- MAMOBX
- ISSN
- 0024-9297
- Scientific domain
- Polymers, paint and wood industries
- Publisher
- American Chemical Society, Washington, DC
- Publication country
- United States
- Document type
- Article
- Language
- English
- Keyword (fr)
- Caprolactone polymère Catalyse enzymatique Cinétique chimique Constante Michaelis Constante vitesse Effet dimensionnel Effet structure Etude expérimentale Monomère Point fusion Polymérisation ouverture cycle Polymérisation solution Réactivité chimique Taille cycle Triacylglycerol lipase Valérolactone polymère Carboxylic ester hydrolases Enzyme Esterases Hydrolases Lactone polymère
- Keyword (en)
- Polycaprolactone Enzymatic catalysis Chemical reaction kinetics Michaelis constant Rate constant Size effect Structure effect Experimental study Monomer Melting point Ring opening polymerization Solution polymerization Chemical reactivity Ring size Triacylglycerol lipase Carboxylic ester hydrolases Enzyme Esterases Hydrolases Lactone polymer
- Keyword (es)
- Caprolactona polímero Catálisis enzimática Cinética química Constante Michaelis Constante velocidad Efecto dimensional Efecto estructura Estudio experimental Monómero Punto fusión Polimerización abertura ciclo Polimerización solución Reactividad química Dimensión ciclo Triacylglycerol lipase Carboxylic ester hydrolases Enzima Esterases Hydrolases Lactona polímero
- Classification
- Pascal
- 001 Exact sciences and technology / 001D Applied sciences / 001D09 Physicochemistry of polymers / 001D09D Organic polymers / 001D09D02 Preparation, kinetics, thermodynamics, mechanism and catalysts / 001D09D02B Polymerization
- Discipline
- Physical chemistry of polymers
- Origin
- Inist-CNRS
- Database
- PASCAL
- INIST identifier
- 17971862
Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS
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DOI
10.1021/ma060668j 
https://dx.doi.org/10.1021/ma060668j
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