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Intermediates of halogen addition to phenylethynes and protonation of phenylethynyl halides. open halovinyl cations, bridged halonium, or phenyl-bridged ions : A substituent effect study by DFT and GIAO-DFT

Author
OKAZAKI, Takao1 2 ; LAALI, Kenneth K1
[1] Department of Chemistry, Kent State University, Kent, Ohio 44242, United States
[2] Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto 615-8510, Japan
Source

Journal of organic chemistry. 2006, Vol 71, Num 26, pp 9643-9650, 8 p ; ref : 12 ref

CODEN
JOCEAH
ISSN
0022-3263
Scientific domain
Biochemistry, molecular biology, biophysics; Organic chemistry
Publisher
American Chemical Society, Washington, DC
Publication country
United States
Document type
Article
Language
English
Keyword (fr)
Cation Cinétique Composé acétylénique Composé aromatique Composé cyclique Composé vinylique Dication organique Déplacement chimique Effet substituant Etude comparative Halogène composé organique Halogène composé Méthode fonctionnelle densité Protonation Solvolyse Spectrométrie RMN Spirane Stabilité Structure électronique Synthèse chimique
Keyword (en)
Cations Kinetics Acetylenic compound Aromatic compound Cyclic compound Vinylic compound Organic dication Chemical shift Substituent effect Comparative study Organic halogen compounds Halogen compound Density functional method Protonation Solvolysis NMR spectrometry Spiran Stability Electronic structure Chemical synthesis
Keyword (es)
Cation Cinética Compuesto acetilénico Compuesto aromático Compuesto cíclico Compuesto vinílico Dicatión orgánico Desplazamiento químico Efecto sustituyente Estudio comparativo Halogeno compuesto Protonación Solvolisis Espectrometría RMN Espirano Estabilidad Estructura electrónica Síntesis química
Classification
Pascal
001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03B Reactivity and mechanisms / 001C03B02 Kinetics and mechanisms

Discipline
Organic chemistry
Origin
Inist-CNRS
Database
PASCAL
INIST identifier
18367089

Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS

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