A new class of SN2 reactions catalyzed by protic solvents : Facile fluorination for isotopic labeling of diagnostic molecules
- Author
- DONG WOOK KIM1 ; AHN, Doo-Sik2 ; DAE YOON CHI1 3 ; OH, Young-Ho2 ; LEE, Sungyul2 ; HEE SEUP KIL1 3 ; SEUNG JUN OH4 ; SANG JU LEE4 ; JAE SEUNG KIM4 ; JIN SOOK RYU4 ; DAE HYUK MOON4
[1] Department of Chemistry, Inha University, 253 Yonghyundong Namgu, Inchon 402-751, Korea, Republic of
[2] College of Environmental Science and Applied Chemistry (BK21), Kyunghee University, Kyungki 449-701, Korea, Republic of
[3] Research Institute of Labeling, FutureChem Co. Ltd., 388-1 Pungnap-2-dong, Songpa-gu, Seoul 138-736, Korea, Republic of
[4] Department of Nuclear Medicine, Asan Medical Center, University of Ulsan College of Medicine, 388-1 Pungnap-2-dong, Songpa-gu, Seoul 138-736, Korea, Republic of - Source
Journal of the American Chemical Society. 2006, Vol 128, Num 50, pp 16394-16397, 4 p ; ref : 13 ref
- CODEN
- JACSAT
- ISSN
- 0002-7863
- Scientific domain
- Biochemistry, molecular biology, biophysics; Chemistry; Organic chemistry; Atomic molecular physics
- Publisher
- American Chemical Society, Washington, DC
- Publication country
- United States
- Document type
- Article
- Language
- English
- Keyword (fr)
- Alcool tertiaire Alcène Catalyseur Composé éthylénique Ether Fluor 18 Fluor composé organique Fluoration Fluorure Formation image Marquage isotopique Mécanisme SN2 Métal alcalin Nucléophile Nucléophilicité Photoinduction Réaction catalytique Réactivité chimique Solvant aprotique Solvant dipolaire Solvant protique Sonde moléculaire Synthèse chimique Transfert électron Vitesse réaction
- Keyword (en)
- Tertiary alcohol Alkene Catalyst Ethylenic compound Ether Fluorine 18 Organic fluorine compounds Fluorination Fluorides Imaging Isotope labelling SN2 mechanism Alkali metal Nucleophile Nucleophilicity Photoinduction Catalytic reaction Chemical reactivity Aprotic solvent Dipolar solvent Protic solvent Molecular probe Chemical synthesis Electron transfer Reaction rate
- Keyword (es)
- Alcohol terciario Alqueno Catalizador Compuesto etilénico Eter Fluoración Fluoruro Formación imagen Marcación isotópica Mecanismo SN2 Metal alcalino Nucleófilo Nucleofilicidad Fotoinducción Reacción catalítica Reactividad química Solvente aprótico Disolvente dipolar Disolvente prótico Aguja molecular Síntesis química Transferencia electrón Velocidad reacción
- Classification
- Pascal
- 001 Exact sciences and technology / 001C Chemistry / 001C01 General and physical chemistry / 001C01A Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry / 001C01A03 Catalysis / 001C01A03A Catalysts: preparations and properties
- Discipline
- General chemistry and physical chemistry
- Origin
- Inist-CNRS
- Database
- PASCAL
- INIST identifier
- 18367631
Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS
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DOI
10.1021/ja0646895 
https://dx.doi.org/10.1021/ja0646895
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