Stereochemistry control of the alternating copolymerization of CO2 and propylene oxide catalyzed by SalenCrX complexes
- Author
- BO LI1 ; RONG ZHANG1 ; LU, Xiao-Bing1
[1] State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012, China - Source
Macromolecules. 2007, Vol 40, Num 7, pp 2303-2307, 5 p ; ref : 16 ref
- CODEN
- MAMOBX
- ISSN
- 0024-9297
- Scientific domain
- Polymers, paint and wood industries
- Publisher
- American Chemical Society, Washington, DC
- Publication country
- United States
- Document type
- Article
- Language
- English
- Keyword (fr)
- Activité catalytique Base Schiff Carbonate copolymère Carbonate polymère Carbone dioxyde Catalyseur complexe Chrome complexe Complexe aryloxy Copolymère aliphatique Copolymère optiquement actif Copolymérisation alternée Copolymérisation catalyseur complexe Copolymérisation ouverture cycle Effet substituant Enantiosélectivité Etude expérimentale Mécanisme réaction Oxirane(méthyl) Polymère aliphatique Polymère optiquement actif Polymère tête à queue Polymérisation stéréoélective Régiospécificité Stéréorégulation Terpolymérisation Cyclohexène carbonate copolymère Propène carbonate copolymère Propène carbonate polymère
- Keyword (en)
- Catalyst activity Schiff base Carbonate copolymer Polycarbonate Carbon dioxide Complex catalyst Chromium complex Aryloxy complex Aliphatic copolymer Optically active copolymer Alternating copolymerization Complex catalyst copolymerization Ring opening copolymerization Substituent effect Enantioselectivity Experimental study Reaction mechanism Oxirane(methyl) Aliphatic polymer Optically active polymer Head to tail polymer Stereoelective polymerization Regiospecificity Stereoregulation Terpolymerization
- Keyword (es)
- Actividad catalítica Base Schiff Carbonato copolímero Carbonato polímero Carbono dióxido Catalizador complejo Cromo complejo Complejo ariloxi Copolímero alifático Copolímero ópticamente activo Copolimerización alternada Copolimerización catalizador complejo Copolimerización abertura ciclo Efecto sustituyente Enantioselectividad Estudio experimental Mecanismo reacción Oxirano(metil) Polímero alifático Polímero ópticamente activo Polímero cabeza a cola Polimerización estereoelectiva Regiospecificidad Estereorregulación Terpolimerización
- Classification
- Pascal
- 001 Exact sciences and technology / 001D Applied sciences / 001D09 Physicochemistry of polymers / 001D09D Organic polymers / 001D09D02 Preparation, kinetics, thermodynamics, mechanism and catalysts / 001D09D02C Copolymerization
- Discipline
- Physical chemistry of polymers
- Origin
- Inist-CNRS
- Database
- PASCAL
- INIST identifier
- 18665155
Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS
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DOI
10.1021/ma062735f 
https://dx.doi.org/10.1021/ma062735f
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