Rearrangement of the 1,1-diphenylethoxyl radical is not concerted but occurs through a bridged intermediate
- Author
- SMEU, Manuel1 2 ; DILABIO, Gino A1
[1] National Institute for Nanotechnology, National Research Council of Canada, 11421 Saskatchewan Drive, Edmonton, Alberta, T6G 2M9, Canada
[2] Department of Physics, University of Alberta, Edmonton, Alberta, T6G 2E1, Canada - Source
Journal of organic chemistry. 2007, Vol 72, Num 12, pp 4520-4523, 4 p ; ref : 21 ref
- CODEN
- JOCEAH
- ISSN
- 0022-3263
- Scientific domain
- Biochemistry, molecular biology, biophysics; Organic chemistry
- Publisher
- American Chemical Society, Washington, DC
- Publication country
- United States
- Document type
- Article
- Language
- English
- Keyword (fr)
- Etude théorique Intermédiaire réaction Mécanisme par étape Méthode fonctionnelle densité Radical libre organique Réaction concertée Transposition chimique Ethoxyle(1,1-diphényl)
- Keyword (en)
- Theoretical study Reaction intermediate Stepwise mechanism Density functional method Organic free radical Concerted reaction Chemical rearrangement
- Keyword (es)
- Estudio teórico Intermediario reacción Mecanismo a etapas Radical libre orgánico Reacción concertada Transposición química
- Classification
- Pascal
- 001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03B Reactivity and mechanisms / 001C03B02 Kinetics and mechanisms
- Pascal
- 001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03B Reactivity and mechanisms / 001C03B04 Free radicals chemistry
- Discipline
- Organic chemistry
- Origin
- Inist-CNRS
- Database
- PASCAL
- INIST identifier
- 18841847
Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS
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DOI
10.1021/jo070126f 
https://dx.doi.org/10.1021/jo070126f
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