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Stereoselective construction of steroidal trans-hydrindanes via intramolecular ester enolate alkylation [1,2]

Author
DEUKJOON KIM; SANGHEE KIM; JAE JEONG LEE; HAK SUNG KIM
Seoul national univ., coll. pharmacy, Kwanak-ku, Seoul 151-742, Korea, Republic of
Source

Tetrahedron letters. 1990, Vol 31, Num 28, pp 4027-4028, 2 p ; ref : 10 ref

CODEN
TELEAY
ISSN
0040-4039
Scientific domain
Biochemistry, molecular biology, biophysics; Organic chemistry
Publisher
Elsevier, Oxford
Publication country
United Kingdom
Document type
Article
Language
English
Keyword (fr)
Alkylation Composé bicyclique Composé homoallylique Composé saturé Cétone Dithioacétal Hétérocycle soufre Réaction intramoléculaire Spirane Stéréosélectivité Pent-4-énoïque acide(«2»-méthyl-«3»-[«2»-(«2»-[tosyloxy] éthyl)-«1,3»-dithian-«2»-ylméthyl]) ester éthyle Spiro [«1,3»-dithiane-«2:5p»-indén-«1p»-one](«7a»-méthyl [octahydro])
Keyword (en)
Alkylation Bicyclic compound Homoallylic compound Saturated compound Ketone Dithioacetal Sulfur heterocycle Intramolecular reaction Spiran Stereoselectivity
Keyword (es)
Alquilación Compuesto bicíclico Compuesto homoalílico Compuesto saturado Cetona Ditioacetal Heterociclo azufre Reacción intramolecular Espirano Estereoselectividad
Classification
Pascal
001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03C Preparations and properties / 001C03C05 Alicyclic compounds, terpenoids, prostaglandins, steroids / 001C03C05A Alicyclic compounds

Discipline
Organic chemistry
Origin
Inist-CNRS
Database
PASCAL
INIST identifier
19380238

Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS

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