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Catalysis of hydrolysis and nucleophilic substitution at the P-N bond of phosphoimidazolide-activated nucleotides in phosphate buffers

Author
KANAVARIOTI, A; ROSENBACH, M. T
Univ. California, chemistry dep., Santa Cruz CA 95064, United States
Source

Journal of organic chemistry. 1991, Vol 56, Num 4, pp 1513-1521, 9 p ; ref : 17 ref

CODEN
JOCEAH
ISSN
0022-3263
Scientific domain
Biochemistry, molecular biology, biophysics; Organic chemistry
Publisher
American Chemical Society, Washington, DC
Publication country
United States
Document type
Article
Language
English
Keyword (fr)
Constante vitesse Effet milieu Hydrolyse Hétérocycle azote Mécanisme réaction PH Purine nucléotide Pyrimidine nucléotide Réaction catalytique Solution tampon Substitution nucléophile Cytidine «5p»-phosphate Guanosine 5p-phosphate Imidazole(«2»-méthyl) Phosphate
Keyword (en)
Rate constant Medium effect Hydrolysis Nitrogen heterocycle Reaction mechanism PH Purine nucleotide Pyrimidine nucleotide Catalytic reaction Buffer solution Nucleophilic substitution
Keyword (es)
Constante velocidad Efecto medio Hidrólisis Heterociclo nitrógeno Mecanismo reacción PH Purina nucleótido Pirimidina nucleótido Reacción catalítica Solución de amortiguación Substitución nucleófila
Classification
Pascal
001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03B Reactivity and mechanisms / 001C03B02 Kinetics and mechanisms

Discipline
Organic chemistry
Origin
Inist-CNRS
Database
PASCAL
INIST identifier
19639575

Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS

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