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Enhanced Reactivity of Monovinyl Acrylates Characterized by Secondary Functionalities Toward Photopolymerization and Michael Addition : Contribution of Intramolecular Effects

Author
KILAMBI, Harini1 ; STANSBURY, Jeffrey W1 2 ; BOWMAN, Christopher N1 2
[1] Department of Chemical and Biological Engineering, University of Colorado, Boulder, Colorado 80309-0424, United States
[2] Biomaterials Research Center, School of Dentistry, University of Colorado Health Sciences Center, Aurora, CO 80045-0508, United States
Source

Journal of polymer science. Part A. Polymer chemistry. 2008, Vol 46, Num 10, pp 3452-3458, 7 p ; ref : 39 ref

CODEN
JPLCAT
ISSN
0887-624X
Scientific domain
Polymers, paint and wood industries
Publisher
Wiley, New York, NY
Publication country
United States
Document type
Article
Language
English
Author keyword
monomer photopolymerization radical polymerization
Keyword (fr)
Acrylate polymère Addition Michaël Carbamate organique Carbonate organique Cinétique chimique Composé bifonctionnel Constante vitesse Cyanoester Effet substituant Effet électronique Etude expérimentale Mercaptoester Monomère Polymérisation masse Polymérisation photochimique Réactivité chimique
Keyword (en)
Acrylate polymer Michael addition Organic carbamate Organic carbonate Chemical reaction kinetics Bifunctional compound Rate constant Cyanoester Substituent effect Electronic effect Experimental study Mercaptoester Monomer Bulk polymerization Photopolymerization Chemical reactivity
Keyword (es)
Acrilato polímero Adición Michael Carbamato orgánico Carbonato orgánico Cinética química Compuesto bifuncional Constante velocidad Cianoester Efecto sustituyente Efecto electrónico Estudio experimental Mercaptoester Monómero Polimerización masa Polimerización fotoquímica Reactividad química
Classification
Pascal
001 Exact sciences and technology / 001D Applied sciences / 001D09 Physicochemistry of polymers / 001D09B Polymers and radiations / 001D09B01 Polymerization

Discipline
Physical chemistry of polymers
Origin
Inist-CNRS
Database
PASCAL
INIST identifier
20276713

Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS

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