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Capture of hydroxymethylene and its fast disappearance through tunnelling

Author
SCHREINER, Peter R1 ; REISENAUER, Hans Peter1 ; PICKARD, Frank C2 ; SIMMONETT, Andrew C2 ; ALLEN, Wesley D2 ; MATYUS, Edit3 ; CSASZAR, Attila G3
[1] Institut für Organische Chemie der Justus-Liebig-Universität, Heinrich-Buff-Ring 58, 35392 Giessen, Germany
[2] Center for Computational Chemistry and Department of Chemistry, University of Georgia, Athens, Georgia 30602, United States
[3] Laboratory of Molecular Spectroscopy, Institute of Chemistry, Eötvös University, PO Box 32, 1518 Budapest, Hungary
Source

Nature (London). 2008, Vol 453, Num 7197, pp 906-909, 4 p ; ref : 30 ref

CODEN
NATUAS
ISSN
0028-0836
Scientific domain
Multidisciplinary
Publisher
Nature Publishing, London
Publication country
United Kingdom
Document type
Article
Language
English
Keyword (fr)
Aldéhyde Barrière énergie Caractérisation Carbène Diradical libre organique Etude théorique Formaldéhyde Glucide Hétérocycle azote Isolement matrice Ligand Métal transition Métathèse Photocatalyse Spectrométrie IR Spectrométrie UV visible Synthèse chimique Tautomère Valence
Keyword (en)
Aldehyde Energy barrier Characterization Carbene Organic free biradical Theoretical study Formaldehyde Carbohydrate Nitrogen heterocycle Matrix isolation Ligand Transition metal Metathesis Photocatalysis Infrared spectrometry Ultraviolet visible spectrometry Chemical synthesis Tautomer Valence
Keyword (es)
Aldehído Barrera energía Caracterización Carbeno Dirradical libre orgánico Estudio teórico Formaldehído Glúcido Heterociclo nitrógeno Aislamiento matriz Ligando Metal transición Metatesis Fotocatálisis Espectrometría IR Espectrometría UV visible Síntesis química Tautómero Valencia
Classification
Pascal
001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03B Reactivity and mechanisms / 001C03B04 Free radicals chemistry

Discipline
Organic chemistry
Origin
Inist-CNRS
Database
PASCAL
INIST identifier
20400942

Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS

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