Stereoselective Stille Coupling of Enantiopure Haloallenes and Alkenylstannanes for the Synthesis of Allenyl Carotenoids. Experimental and Computational Studies
- Author
- VAZ, Belén1 ; PEREIRA, Raquel1 ; PEREZ, Martin1 ; ALVAREZ, Rosana1 ; DE LERA, Angel R1
[1] Departamento de Química Orgánica, Facultad de Quimica, Universidade de Vigo, 36310 Vigo, Spain - Source
Journal of organic chemistry. 2008, Vol 73, Num 17, pp 6534-6541, 8 p
- CODEN
- JOCEAH
- ISSN
- 0022-3263
- Scientific domain
- Biochemistry, molecular biology, biophysics; Organic chemistry
- Publisher
- American Chemical Society, Washington, DC
- Publication country
- United States
- Document type
- Article
- Language
- English
- Keyword (fr)
- Caroténoïde Catalyseur Complexation Complexe de palladium Composé allénique Composé chiral Composé d'halogène Configuration Copulation Stille DMF Dérivé du cyclohexane Etude expérimentale Etude théorique Inversion configuration Ligand Mécanisme SN2 Méthode fonctionnelle densité Oxydation Palladium Complexe Palladium Paramètre thermodynamique Réaction croisée Rétention configuration Solvant Stannane organique Stéréosélectivité Synthèse chimique Métal transition Complexe Métal transition Platinoïde Complexe Platinoïde
- Keyword (en)
- Carotenoid Catalyst Complexation Palladium complex Allenic compound Chiral compound Halogen compound Configuration Stille coupling N,N-Dimethylformamide Cyclohexane derivatives Experimental study Theoretical study Configuration inversion Ligand SN2 mechanism Density functional method Oxidation Palladium Complexes Palladium Thermodynamic parameter Cross reaction Configuration retention Solvent Organic stannane Stereoselectivity Chemical synthesis Transition metal Complexes Transition metal Platinoid Complexes Platinoid
- Keyword (es)
- Carotenoide Catalizador Complexación Paladio complejo Compuesto alénico Compuesto quiral Halogeno compuesto Configuración Stille copulación Dimetilformamida Ciclohexano derivado Estudio experimental Estudio teórico Inversión configuración Ligando Mecanismo SN2 Oxidación Paladio Complejo Paladio Parámetro termodinámico Reacción cruzada Retención configuración Solvente Estannano orgánico Estereoselectividad Síntesis química Metal transición Complejo Metal transición Platinoide Complejo Platinoide
- Classification
- Pascal
- 001 Exact sciences and technology / 001C Chemistry / 001C01 General and physical chemistry / 001C01A Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry / 001C01A03 Catalysis / 001C01A03A Catalysts: preparations and properties
- Pascal
- 001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03B Reactivity and mechanisms / 001C03B02 Kinetics and mechanisms
- Pascal
- 001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03C Preparations and properties / 001C03C05 Alicyclic compounds, terpenoids, prostaglandins, steroids / 001C03C05A Alicyclic compounds
- Discipline
- General chemistry and physical chemistry Organic chemistry
- Origin
- Inist-CNRS
- Database
- PASCAL
- INIST identifier
- 20623010
Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS
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DOI
10.1021/jo800756b 
https://dx.doi.org/10.1021/jo800756b
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