Réarrangement thermique de N-acyl-2,2-diméthylaziridines substituées : Une étude mécanistique
- Other title
- Thermal rearrangement of substituted N-acyl-2,2-dimethyl aziridines : a mechanistic study (en)
- Author
- BESBES, Néji1 ; AYED, Tahra2 ; PALE, Patrick3 ; TANGOUR, Bahoueddine2
[1] Unité de matériaux, centre de recherche et de technologie, technopole de Bordj Cédria, B.P. 95, 2050 Hammam Lif, Tunisia
[2] Unité de recherche chimie théorique et réactivité, institut préparatoire aux études d'ingénieurs d'El Manar, campus universitaire, El Manar, 2092 Tunis, Tunisia
[3] Laboratoire de synthèse et réactivité organique (UMR 7123 CNRS), institut de chimie, université Louis-Pasteur, 4, rue Biaise-Pascal, 67000 Strasbourg, France - Source
Comptes rendus. Chimie. 2008, Vol 11, Num 10, pp 1283-1288, 6 p ; ref : 14 ref
- Publisher
- Elsevier, Paris
- Publication country
- France
- Document type
- Article
- Language
- French
- Author keyword
- Calculs théoriques N-acylaziridines N-méthallylamides Oxazolines Réarrangement Thermolyse Zwitterion États de transitions
- Keyword (fr)
- Calcul Carboxamide Cinétique Cétone Dérivé de l'aziridine Effet substituant Etat transition Etude théorique Hétérocycle azote Hétérocycle oxygène azote Ion amphotère Mécanisme réaction Méthode fonctionnelle densité Oxazoline dérivé Pyrolyse Réaction thermique Thermodynamique Transposition chimique
- Keyword (en)
- Calculation Carboxamide Kinetics Ketone Aziridine derivatives Substituent effect Transition state Theoretical study Nitrogen heterocycle Oxygen nitrogen heterocycle Zwitterion Reaction mechanism Density functional method Oxazoline derivatives Pyrolysis Thermal reaction Thermodynamics Chemical rearrangement
- Keyword (es)
- Cálculo Carboxamida Cinética Cetona Efecto sustituyente Estado transitorio Estudio teórico Heterociclo nitrógeno Heterociclo oxígeno nitrógeno Ión anfotérico Mecanismo reacción Oxazolina derivado Pirólisis Reacción térmica Termodinámica Transposición química
- Classification
- Pascal
- 001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03B Reactivity and mechanisms / 001C03B02 Kinetics and mechanisms
- Pascal
- 001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03C Preparations and properties / 001C03C06 Heterocyclic compounds / 001C03C06B Heterocyclic compounds with only one n hetero atom and condensed derivatives
- Pascal
- 001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03C Preparations and properties / 001C03C06 Heterocyclic compounds / 001C03C06D Heterocyclic compounds with n hetero atom and also o and/or s, se, te hetero atoms
- Discipline
- Organic chemistry
- Origin
- Inist-CNRS
- Database
- PASCAL
- INIST identifier
- 20876556
Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS
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DOI
10.1016/j.crci.2008.07.002 
https://dx.doi.org/10.1016/j.crci.2008.07.002
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