Synthesis, including asymmetric synthesis, of 3-oxabicyclo[3.1.0]hexanes and bicyclo[3.1.0]hexanes by the 1,5-CH insertion of cyclopropylmagnesium carbenoids as the key reaction
- Author
- SATOH, Tsuyoshi1 ; TSURU, Takahiro1 ; IKEDA, Shotaro1 ; MIYAGAWA, Toshifumi1 ; MOMOCHI, Hitoshi1 ; KIMURA, Tsutomu1
[1] Graduate School of Chemical Sciences and Technology, Tokyo University of Science, Ichigaya-funagawara-machi 12, Shinjuku-ku, Tokyo 162-0826, Japan - Source
Tetrahedron (Oxford. Print). 2012, Vol 68, Num 4 ; 937, 1071-1084 [15 p.] ; ref : 23 ref
- CODEN
- TETRAB
- ISSN
- 0040-4020
- Scientific domain
- Organic chemistry
- Publisher
- Elsevier, Kidlington
- Publication country
- United Kingdom
- Document type
- Article
- Language
- English
- Author keyword
- 1,5-CH insertion 3-Oxabicyclo[3.1.0]hexane Cyclopropane Cyclopropylmagnesium carbenoid Magnesium carbenoid
- Keyword (fr)
- Addition chimique Basse température Carbonyle Composé Carbénoïde Composé insaturé Cétone Dérivé du cyclopropane Dérivé du toluène Ether Groupe fonctionnel Hétérocycle oxygène Magnésium Réaction échange Sulfoxyde Synthèse asymétrique Synthèse chimique 3-Oxabicyclo[3.1.0]hexane dérivé Bicyclo[3.1.0]hexane dérivé Lithium amidure(diisopropyl) Magnésium(isopropyl) chlorure Sodium amidure(bis[triméthylsilyl])
- Keyword (en)
- Addition reaction Low temperature Carbonyl Compounds Carbenoid Unsaturated compound Ketone Cyclopropane derivatives Toluene derivatives Ether Functional group Oxygen heterocycle Magnesium Exchange reaction Sulfoxide Asymmetric synthesis Chemical synthesis Lithium diisopropylamide
- Keyword (es)
- Adición química Baja temperatura Carbonilo Compuesto Carbenoide Compuesto insaturado Cetona Ciclopropano derivado Tolueno derivado Eter Grupo funcional Heterociclo oxígeno Magnesio Reacción intercambio Sulfóxido Síntesis asimétrica Síntesis química
- Classification
- Pascal
- 001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03C Preparations and properties / 001C03C05 Alicyclic compounds, terpenoids, prostaglandins, steroids / 001C03C05A Alicyclic compounds
- Pascal
- 001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03C Preparations and properties / 001C03C06 Heterocyclic compounds / 001C03C06A Heterocyclic compounds with o, s, se, te hetero atom and condensed derivatives
- Discipline
- Organic chemistry
- Origin
- Inist-CNRS
- Database
- PASCAL
- INIST identifier
- 25406520
Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS
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DOI
10.1016/j.tet.2011.11.085 
https://dx.doi.org/10.1016/j.tet.2011.11.085
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