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Highly Enantioselective Synthesis of Spiro[cyclohexanone-oxindoles] and Spiro[cyclohexanone-pyrazolones] by Asymmetric Cascade [5+1] Double Michael Reactions

Author
BIN WU1 ; JIAN CHEN1 ; LI, Mei-Qiu1 ; ZHANG, Jin-Xin1 ; XU, Xiao-Ping1 ; JI, Shun-Jun1 ; WANG, Xing-Wang1
[1] Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China
Source

European journal of organic chemistry (Print). 2012, Num 7, pp 1318-1327, 10 p ; ref : 33 ref

ISSN
1434-193X
Scientific domain
Organic chemistry
Publisher
Wiley-VCH, Weinheim
Publication country
Germany
Document type
Article
Language
English
Author keyword
Enantioselectivity Michael addition Nitrogen heterocycles Organocatalysis Spiro compounds
Keyword (fr)
Activité biologique Addition Michaël Alcaloïde Amine Catalyse Cétone Dérivé de l'indole Dérivé de la quinoléine Dérivé de la quinuclidine Dérivé du pyrazole Enantiosélectivité Excès énantiomère Hétérocycle azote Lactame Protection Réaction catalytique Réaction successive Spirane Stéréosélectivité Synthèse asymétrique Synthèse chimique α-Aminoacide 2,3-Diazaspiro[4.5]déc-1-ène dérivé Catalyseur organique Cinchonane dérivé Cyclohexanone dérivé Epiquinine Indolin-2-one dérivé Indoline dérivé Phénylglycine Pyrazolone dérivé Spiro[cyclohexane-1,3\'-indole] dérivé
Keyword (en)
Biological activity Michael addition Alkaloid Amine Catalysis Ketone Indole derivatives Quinoline derivatives Quinuclidine derivatives Pyrazole derivatives Enantioselectivity Enantiomeric excess Nitrogen heterocycle Lactam Protection Catalytic reaction Successive reaction Spiran Stereoselectivity Asymmetric synthesis Chemical synthesis α-Aminoacid Organocatalyst Cyclohexanone derivative
Keyword (es)
Actividad biológica Adición Michael Alcaloide Amina Catálisis Cetona Indol derivado Quinolina derivado Pirazol derivado Enantioselectividad Exceso enantiómero Heterociclo nitrógeno Lactamo Protección Reacción catalítica Reacción consecutiva Espirano Estereoselectividad Síntesis asimétrica Síntesis química α-Aminoácido
Classification
Pascal
001 Exact sciences and technology / 001C Chemistry / 001C01 General and physical chemistry / 001C01A Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry / 001C01A03 Catalysis / 001C01A03A Catalysts: preparations and properties

Pascal
001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03C Preparations and properties / 001C03C06 Heterocyclic compounds / 001C03C06B Heterocyclic compounds with only one n hetero atom and condensed derivatives

Pascal
001 Exact sciences and technology / 001C Chemistry / 001C03 Organic chemistry / 001C03C Preparations and properties / 001C03C06 Heterocyclic compounds / 001C03C06C Heterocyclic compounds with several n hetero atoms in the same ring, in separated rings or in fused rings

Discipline
General chemistry and physical chemistry Organic chemistry
Origin
Inist-CNRS
Database
PASCAL
INIST identifier
25556352

Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS

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