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The influence of the metal (Al, Cr and Co) and the substituents of the porphyrin in controlling the reactions involved in the copolymerization of propylene oxide and cyclic anhydrides by porphyrin metal(III) complexes

Author
BERNARD, Alexandre1 ; CHATTERJEE, Chandrani1 ; CHISHOLM, Malcolm H1
[1] Department of Chemistry and Biochemistry, The Ohio State University, Columbus, OH 43210, United States
Source

Polymer (Guildford). 2013, Vol 54, Num 11, pp 2639-2646, 8 p ; ref : 18 ref

CODEN
POLMAG
ISSN
0032-3861
Scientific domain
Polymers, paint and wood industries
Publisher
Elsevier, Kidlington
Publication country
United Kingdom
Document type
Article
Language
English
Author keyword
(Porphyrin)M(III)catalyst systems Diblock poly(ester-co-carbonates) Ring opening copolymerization
Keyword (fr)
Activité catalytique Anhydride organique Base Lewis Carbonate copolymère Catalyseur complexe Complexe alcoxy Complexe chloro Complexe d'aluminium Complexe de chrome Complexe de cobalt Composé du phosphore Copolymère aliphatique Copolymérisation alternée Copolymérisation catalyseur complexe Copolymérisation ouverture cycle Dioxyde de carbone Effet coordinat Etude expérimentale Maléate polymère Oxirane(méthyl) Phtalate copolymère Phtalate polymère Polymère aliphatique Porphyrine métallique Régiosélectivité Succinate copolymère Succinate polymère Terpolymérisation Propène carbonate copolymère Propène maléate copolymère Propène maléate polymère Propène phtalate copolymère Propène phtalate polymère Propène succinate polymère Ester copolymère Ester polymère
Keyword (en)
Catalyst activity Organic anhydride Lewis base Carbonate copolymer Complex catalyst Alkoxy complex Chloro complex Aluminium complex Chromium complex Cobalt complex Phosphorus compound Aliphatic copolymer Alternating copolymerization Complex catalyst copolymerization Ring opening copolymerization Carbon dioxide Ligand effect Experimental study Maleate polymer Oxirane(methyl) Phthalate copolymer Phthalate polymer Aliphatic polymer Metalloporphyrin Regioselectivity Succinate copolymer Polysuccinate Terpolymerization Ester copolymer Ester polymer
Keyword (es)
Actividad catalítica Anhídrido orgánico Base Lewis Carbonato copolímero Catalizador complejo Complejo alcoxi Complejo cloro Aluminio complejo Cromo complejo Cobalto complejo Fósforo compuesto Copolímero alifático Copolimerización alternada Copolimerización catalizador complejo Copolimerización abertura ciclo Carbono dióxido Efecto ligando Estudio experimental Maleato polímero Oxirano(metil) Ftalato copolímero Ftalato polímero Polímero alifático Porfirina metálica Regioselectividad Succinato copolímero Succinato polímero Terpolimerización Ester copolímero Ester polímero
Classification
Pascal
001 Exact sciences and technology / 001D Applied sciences / 001D09 Physicochemistry of polymers / 001D09D Organic polymers / 001D09D02 Preparation, kinetics, thermodynamics, mechanism and catalysts / 001D09D02C Copolymerization

Discipline
Physical chemistry of polymers
Origin
Inist-CNRS
Database
PASCAL
INIST identifier
27335209

Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS

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