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Supramolecular photochemistry of the [(η5-C5H4CH2CH2NH3+)2Mo2(CO)6][PF6-]2 complex. Chemical ramifications of a tentacle ligand covalently bonded nearby to a reactive metal center

Author
AVEY, A; WEAKLEY, T. J. R; TYLER, D. R
Univ. Oregon, dep. chemistry, Eugene OR 97403, United States
Source

Journal of the American Chemical Society. 1993, Vol 115, Num 17, pp 7706-7715 ; ref : 50 ref

CODEN
JACSAT
ISSN
0002-7863
Scientific domain
Biochemistry, molecular biology, biophysics; Chemistry; Organic chemistry; Atomic molecular physics
Publisher
American Chemical Society, Washington, DC
Publication country
United States
Document type
Article
Language
English
Keyword (fr)
Complexe cationique Complexe dinucléaire Complexe hapto Diffraction RX Dismutation Etude expérimentale Furane(tétrahydro) Liaison métal métal Molybdène Carbonyle Complexe Mécanisme réaction Photolyse Rayonnement visible Solution non aqueuse Solvant organique Structure moléculaire Molybdène(η5-[1-(2-ammonioéthyl)cyclopentadiényl]) complexe Métal transition Carbonyle Complexe
Keyword (en)
Cationic complex Dinuclear complex Hapto complex X ray diffraction Disproportionation Experimental study Tetrahydrofurane Metal metal bond Molybdenum Carbonyl Complexes Reaction mechanism Photolysis Visible radiation Non aqueous solution Organic solvent Molecular structure Transition metal Carbonyl Complexes
Keyword (es)
Complejo catiónico Complejo dinuclear Complejo hapto Difracción RX Dismutación Estudio experimental Enlace metal metal Molibdeno Carbonilo Complejo Mecanismo reacción Fotolisis Radiación visible Solución no acuosa Solvente orgánico Estructura molecular Metal transición Carbonilo Complejo
Classification
Pascal
001 Exact sciences and technology / 001C Chemistry / 001C01 General and physical chemistry / 001C01F Physical chemistry of induced reactions (with radiations, particles and ultrasonics) / 001C01F01 Photochemistry

Discipline
General chemistry and physical chemistry
Origin
Inist-CNRS
Database
PASCAL
INIST identifier
3753481

Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS

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